MOCVD of tungsten nitride thin films using W(CO) 6 and NH 3...

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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C438S685000

Reexamination Certificate

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07094691

ABSTRACT:
A method of forming a tungsten nitride thin film in an integrated circuit includes preparing a silicon substrate on a silicon wafer and placing the silicon wafer in a heatable chuck in a CVD vacuum chamber; placing a known quantity of a tungsten source in a variable-temperature bubbler to provide a gaseous tungsten source; setting the variable-temperature bubbler to a predetermined temperature; passing a carrier gas through the variable-temperature bubbler and carrying the gaseous tungsten source with the carrier gas into the CVD vacuum chamber; introducing a nitrogen-containing reactant gas into the CVD vacuum chamber; reacting the gaseous tungsten source and the nitrogen-containing reactant gas above the surface of the silicon wafer in a deposition process to deposit a WxNythin film on the surface of the silicon wafer; and completing the integrated circuit containing the WxNythin film.

REFERENCES:
patent: 5429989 (1995-07-01), Fiordalice et al.
patent: 6767582 (2004-07-01), Elers
patent: 2003/0198587 (2003-10-01), Kaloyeros et al.
patent: 2004/0142557 (2004-07-01), Levy et al.
Yu et al. Critical Surface Reactions in the CVD of tungsten by WF6and WF6/SIH4Mixtures. Materials Research Society. 1989. pp 221-230.

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