Methods of depositing highly selective transparent ashable...

Semiconductor device manufacturing: process – Coating of substrate containing semiconductor region or of... – Insulative material deposited upon semiconductive substrate

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C438S780000, C438S738000, C438S740000, C257SE21259, C257SE21264, C216S049000, C216S041000

Reexamination Certificate

active

07981810

ABSTRACT:
The present invention addresses this need by providing a method for forming transparent PECVD deposited ashable hardmasks (AHMs) that have high plasma etch selectivity to underlying layers. Methods of the invention involve depositing the AHM using dilute hydrocarbon precursor gas flows and/or low process temperatures. The AHMs produced are transparent (having absorption coefficients of less than 0.1 in certain embodiments). The AHMs also have the property of high selectivity of the hard mask film to the underlying layers for successful integration of the film, and are suitable for use with 193 nm generation and below lithography schemes wherein high selectivity of the hard mask to the underlying layers is required. The lower temperature process also allows reduction of the overall thermal budget for a wafer.

REFERENCES:
patent: 4209357 (1980-06-01), Gorin et al.
patent: 4668261 (1987-05-01), Chatzipetros et al.
patent: 4863493 (1989-09-01), Kotani et al.
patent: 4863760 (1989-09-01), Schantz et al.
patent: 5231057 (1993-07-01), Doki et al.
patent: 5261250 (1993-11-01), Missimer
patent: 5378316 (1995-01-01), Franke et al.
patent: 5470661 (1995-11-01), Bailey et al.
patent: 5670066 (1997-09-01), Barnes et al.
patent: 6030591 (2000-02-01), Tom et al.
patent: 6035803 (2000-03-01), Robles et al.
patent: 6041734 (2000-03-01), Raoux et al.
patent: 6066209 (2000-05-01), Sajoto et al.
patent: 6150719 (2000-11-01), Saia et al.
patent: 6241793 (2001-06-01), Lee et al.
patent: 6286321 (2001-09-01), Glater
patent: 6319299 (2001-11-01), Shih et al.
patent: 6331480 (2001-12-01), Tsai et al.
patent: 6465051 (2002-10-01), Sahin et al.
patent: 6478924 (2002-11-01), Shamouilian et al.
patent: 6541397 (2003-04-01), Bencher
patent: 6573030 (2003-06-01), Fairbairn et al.
patent: 6617553 (2003-09-01), Ho et al.
patent: 6777349 (2004-08-01), Fu et al.
patent: 6967072 (2005-11-01), Latchford et al.
patent: 7223526 (2007-05-01), Fairbairn et al.
patent: 7314506 (2008-01-01), Vininski et al.
patent: 7323401 (2008-01-01), Ramaswamy et al.
patent: 7381644 (2008-06-01), Subramonium et al.
patent: 7820556 (2010-10-01), Hsu et al.
patent: 2001/0021491 (2001-09-01), Chen et al.
patent: 2002/0182848 (2002-12-01), Joseph et al.
patent: 2003/0044532 (2003-03-01), Lee et al.
patent: 2004/0016972 (2004-01-01), Singh et al.
patent: 2004/0018750 (2004-01-01), Sophie et al.
patent: 2004/0023502 (2004-02-01), Tzou et al.
patent: 2004/0140506 (2004-07-01), Singh et al.
patent: 2004/0180551 (2004-09-01), Biles et al.
patent: 2004/0224504 (2004-11-01), Gadgil
patent: 2004/0266195 (2004-12-01), Dokumaci et al.
patent: 2005/0042889 (2005-02-01), Lee et al.
patent: 2005/0098119 (2005-05-01), Burger et al.
patent: 2005/0112506 (2005-05-01), Czech et al.
patent: 2006/0091559 (2006-05-01), Nguyen et al.
patent: 2006/0154086 (2006-07-01), Fuller et al.
patent: 2006/0197881 (2006-09-01), Kang et al.
patent: 2006/0205223 (2006-09-01), Smayling
patent: 2007/0048674 (2007-03-01), Wells
patent: 2007/0059913 (2007-03-01), King et al.
patent: 2007/0125762 (2007-06-01), Cui et al.
patent: 2007/0128538 (2007-06-01), Fairbairn et al.
patent: 2007/0166546 (2007-07-01), Ichikawa et al.
patent: 2007/0166979 (2007-07-01), Wang et al.
patent: 2007/0247073 (2007-10-01), Paterson et al.
patent: 2008/0128907 (2008-06-01), Yang et al.
patent: 2008/0242912 (2008-10-01), Letessier et al.
patent: 2008/0254641 (2008-10-01), Kobayashi et al.
patent: 2009/0182180 (2009-07-01), Huang et al.
patent: 2009/0305516 (2009-12-01), Hsu et al.
patent: 2010/0151691 (2010-06-01), Henri et al.
patent: 2005/048367 (2005-05-01), None
Subramonium et al., “Pulsed PECVD Method for Modulating Hydrogen Content in Hard Mask”, U.S. Appl. No. 11/318,269, filed Dec. 23, 2005.
Ikeda et al., “Top-PECVD”: A New Conformal Plasma Enhanced CVD Technology using TEOS, Ozone and Pulse-modulated RF Plasma,' 1992 IEEE, pp. 11.2.1-11.2.4.
U.S. Office Action mailed Dec. 14, 2006, from U.S. Appl. No. 11/318,269.
Subramonium et al., “Methods of Depositing Stable and Hermetic Ashable Hardmask Films,” Novellus Systems, Inc., U.S. Appl. No. 11/710,377, filed Feb. 22, 2007, pp. 1-26.
Notice of Allowance and Fee Due mailed May 7, 2007 from U.S. Appl. No. 11/318,269.
Allowed Claims from U.S. Appl. No. 11/318,269.
Fang et al., “Methods of Improving Ashable Hardmask Adhesion to Metal layers,” Novellus Systems, Inc., U.S. Appl. No. 11/612,382, filed Dec. 18, 2006.
U.S. Office Action mailed Oct. 9, 2007, from U.S. Appl. No. 11/612,382.
Grill, et al. “Diamondlike carbon films by rf plasma-assisted chemical vapor deposition from acetylene,” IBM J. Res. Develop., vol. 34, No. 6, Nov. 1990, pp. 849-857.
Callegari et al., “Optical properties of hydrogenated amorphous-carbon film for attenuated phase-shift mask applications,” J. Vac. Sci. Technol. B 11(6), Nov./Dec. 1993, pp. 2697-2699.
Grill, A., “Diamond-like carbon: state of the art,” Diamond and Related Materials 8 (1999) 428-434.
Grill, A., “Plasma-deposited diamondlike carbon and related materials,” IBM Journal of Research and Development, vol. 43, ½, 1999, http://research.ibm.com/journal/rd/431/grill.html. 14 pages.
Kragler et al., “Scanning tunneling microscopy based lithography employing amorphous hydrogenated carbon as a high resolution resist mask,” Appl. Phys. Lett. 67 (8), Aug. 21, 1995, pp. 1163-1165.
Subramonium et al., “Pulsed PECVD Method for Modulating Hydrogen Content in Hard Mask,” Novellus Systems, Inc., U.S. Appl. No. 12/048,967, filed Mar. 14, 2008.
Subramonium et al., “Methods and Apparatus for Plasma-Based Deposition,” Novellus Systems, Inc., U.S. Appl. No. 11/849,208, filed Aug. 31, 2007.
U.S. Final Office Action mailed May 13, 2008, from U.S. Appl. No. 11/612,382.
U.S. Office Action mailed Aug. 19, 2008, from U.S. Appl. No. 11/612,382.
Subramonium et al., “Methods of Depositing Smooth and Conformal Ashable Hard Mask Films,” Novellus Systems, Inc., U.S. Appl. No. 12/163,670, filed Jun. 27, 2008.
Hsu et al., “Method for Purifying Acetylene Gas for Use In Semiconductor Processes,” Novellus Systems, Inc., U.S. Appl. No. 12/133,223, filed Jun. 4, 2008.
U.S. Office Action mailed Jan. 5, 2009, from U.S. Appl. No. 11/710,377.
Henri, et al., Method for Improved Thickness Repeatability of PECVD Deposited Carbon Films, Novellus Systems, Inc., U.S. Appl. No. 12/334,220, filed Dec. 12, 2008.
U.S. Office Action mailed May 12, 2009, from U.S. Appl. No. 11/612,382.
U.S. Appl. No. 11/710,377, Office Action mailed Aug. 19, 2009.
U.S. Appl. No. 12/133,223, Office Action mailed Aug. 19, 2009.
U.S. Appl. No. 11/612,382, Office Action mailed Dec. 9, 2009.
U.S. Appl. No. 12/133,223, Office Action mailed Dec. 21, 2009.
U.S. Appl. No. 12/133,223, Notice of Allowance mailed Mar. 2, 2010.
U.S. Appl. No. 11/710,377, Office Action mailed Mar. 31, 2010.
U.S. Appl. No. 11/612,382, Office Action mailed Mar. 26, 2010.
U.S. Appl. No. 12/766,721, “Methods For Forming Conductive Carbon Films by PECVD”, Fox et al., filed Apr. 23, 2010.
U.S. Appl. No. 12/786,842, “Method for purifying acetylene gas for use in semiconductor processes”, Hsu et al., filed May 25, 2010.
Korean Office Action mailed Jun. 1, 2010 for U.S. Appl. No. 2009-0048358.
U.S. Appl. No. 11/849,208, Office Action mailed Sep. 3, 2010.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Methods of depositing highly selective transparent ashable... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Methods of depositing highly selective transparent ashable..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Methods of depositing highly selective transparent ashable... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-2652683

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.