Methods for forming all tungsten contacts and lines

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C438S653000, C438S654000, C438S643000, C438S648000, C438S656000, C257S486000, C257S751000, C257S763000, C257SE21168, C257SE21592, C257SE21476

Reexamination Certificate

active

08053365

ABSTRACT:
Novel low-resistivity tungsten film stack schemes and methods for depositing them are provided. The film stacks include a mixed tungsten/tungsten-containing compound (e.g., WC) layer as a base for deposition of tungsten nucleation and/or bulk layers. According to various embodiments, these tungsten rich layers may be used as barrier and/or adhesion layers in tungsten contact metallization and bitlines. Deposition of the tungsten-rich layers involves exposing the substrate to a halogen-free organometallic tungsten precursor. The mixed tungsten/tungsten carbide layer is a thin, low resistivity film with excellent adhesion and a good base for subsequent tungsten plug or line formation.

REFERENCES:
patent: 4746375 (1988-05-01), Iacovangelo
patent: 4804560 (1989-02-01), Shioya et al.
patent: 5028565 (1991-07-01), Chang et al.
patent: 5227329 (1993-07-01), Kobayashi et al.
patent: 5250329 (1993-10-01), Miracky et al.
patent: 5326723 (1994-07-01), Petro et al.
patent: 5391394 (1995-02-01), Hansen
patent: 5661080 (1997-08-01), Hwang et al.
patent: 5726096 (1998-03-01), Jung
patent: 5795824 (1998-08-01), Hancock
patent: 5804249 (1998-09-01), Sukharev et al.
patent: 5817576 (1998-10-01), Tseng et al.
patent: 5926720 (1999-07-01), Zhao et al.
patent: 5956609 (1999-09-01), Lee et al.
patent: 6001729 (1999-12-01), Shinriki et al.
patent: 6017818 (2000-01-01), Lu
patent: 6037263 (2000-03-01), Chang
patent: 6066366 (2000-05-01), Berenbaum et al.
patent: 6099904 (2000-08-01), Mak et al.
patent: 6107200 (2000-08-01), Takagi et al.
patent: 6143082 (2000-11-01), McInerney et al.
patent: 6174812 (2001-01-01), Hsiung et al.
patent: 6206967 (2001-03-01), Mak et al.
patent: 6245654 (2001-06-01), Shih et al.
patent: 6265312 (2001-07-01), Sidhwa et al.
patent: 6277744 (2001-08-01), Yuan et al.
patent: 6294468 (2001-09-01), Gould-Choquette et al.
patent: 6297152 (2001-10-01), Itoh et al.
patent: 6309966 (2001-10-01), Govindarajan et al.
patent: 6355558 (2002-03-01), Dixit et al.
patent: 6404054 (2002-06-01), Oh et al.
patent: 6551929 (2003-04-01), Kori et al.
patent: 6566250 (2003-05-01), Tu et al.
patent: 6566262 (2003-05-01), Rissman et al.
patent: 6607976 (2003-08-01), Chen et al.
patent: 6635965 (2003-10-01), Lee et al.
patent: 6706625 (2004-03-01), Sudijono et al.
patent: 6720261 (2004-04-01), Bhowmik et al.
patent: 6740585 (2004-05-01), Yoon et al.
patent: 6797340 (2004-09-01), Fang et al.
patent: 6844258 (2005-01-01), Fair et al.
patent: 6861356 (2005-03-01), Matsuse et al.
patent: 6902763 (2005-06-01), Elers et al.
patent: 6936538 (2005-08-01), Byun
patent: 6939804 (2005-09-01), Lai et al.
patent: 6962873 (2005-11-01), Park
patent: 7005372 (2006-02-01), Levy et al.
patent: 7141494 (2006-11-01), Lee et al.
patent: 7157798 (2007-01-01), Fair et al.
patent: 7211144 (2007-05-01), Lu et al.
patent: 7262125 (2007-08-01), Wongsenakhum et al.
patent: 7429402 (2008-09-01), Gandikota et al.
patent: 7589017 (2009-09-01), Chan et al.
patent: 7655567 (2010-02-01), Gao et al.
patent: 7691749 (2010-04-01), Levy et al.
patent: 2001/0008808 (2001-07-01), Gonzalez
patent: 2001/0014533 (2001-08-01), Sun
patent: 2001/0015494 (2001-08-01), Ahn
patent: 2001/0044041 (2001-11-01), Badding et al.
patent: 2002/0090796 (2002-07-01), Desai et al.
patent: 2002/0177316 (2002-11-01), Miller et al.
patent: 2003/0059980 (2003-03-01), Chen et al.
patent: 2003/0104126 (2003-06-01), Fang et al.
patent: 2003/0127043 (2003-07-01), Lu et al.
patent: 2004/0044127 (2004-03-01), Okubo et al.
patent: 2004/0202786 (2004-10-01), Wongsenakhum et al.
patent: 2004/0206267 (2004-10-01), Sambasivan et al.
patent: 2005/0136594 (2005-06-01), Kim
patent: 2006/0003581 (2006-01-01), Johnston et al.
patent: 2006/0094238 (2006-05-01), Levy et al.
patent: 2009/0149022 (2009-06-01), Chan et al.
patent: WO01/27347 (2001-04-01), None
Ken K. Lai and H. Henry Lamb,Precursors for Organometallic Chemical Vapor Deposition of Tungsten Carbide Films, 1995, Chemistry Material, pp. 2284-2292.
U.S. Final Office Action mailed Apr. 28, 2009, from U.S. Appl. No. 11/782,570.
U.S. Office Action mailed Apr. 3, 2009, from U.S. Appl. No. 11/305,368.
U.S. Final Office Action mailed Feb. 26, 2009, from U.S. Appl. No. 11/265,531.
U.S. Notice of Allowance mailed May 4, 2009 from U.S. Appl. No. 11/265,531.
Allowed Claims from U.S. Appl. No. 11/265,531.
U.S. Final Office Action mail Feb. 25, 2009, from U.S. Appl. No. 11/349,035.
U.S. Office Action mailed Jun. 4, 2009, from U.S. Appl. No. 11/349,035.
Ken K. Lai and H. Henry Lamb, Precursors for Organometallic Chemical Vapor Deposition of Tungsten Carbide Films, 1995, Chemistry Material, pp. 2284-2292.
U.S. Office Action mailed Jun. 24, 2009 from U.S. Appl. No. 12/030,645.
U.S. Office Action mailed Aug. 5, 2009, from U.S. Appl. No. 11/951,236.
Ashtiani et al., “Ternary Tungsten-Containing Resistive Thin Films,” Novellus Systems, Inc., U.S. Appl. No. 12/363,330, filed Jan. 30, 2009.
Chandrashekar et al., “Method for Depositing Thin Tungsten Film With Low Resistivity and Robust Micro-Adhesion Characteristics,” Novellus Systems, Inc., U.S. Appl. No. 12/407,541, filed Mar. 19, 2009.
Lee et al., PCT Search Report, Completed Oct. 15, 2004, PCT/US2004/006940, Int'l filing May 3, 2004.
Lee et al., Written Opinion, Completed Oct. 15, 2004, PCT/US2004/006940, Int'l filing May 3, 2004.
George et al., “Surface Chemistry for atomic Layer Growth”, J. Phys. Chem, 1996, vol. 100, No. 31, pp. 13121-13131.
Bell et al., “Batch Reactor Kinetic Studies of Tungsten LPCVD from Silane and Tungsten Hexafluoride”, J. Electrochem. Soc., Jan. 1996, Vol. 143, No. 1, pp. 296-302.
Klaus et al., “Atomic layer deposition of tungsten using sequential surface chemistry with a sacrificial stripping reaction”, Thin Solid Films 360 (2000) 145-153.
Klaus et al., “Atomically Controlled Growth of Tungsten and Tungsten Nitride Using Sequential Surface Reactions,” Applied Surface Science, 162-163, (2000) 479-491.
Li et al., “Deposition of WNxCyThin Films by ALCVD™ Method for Diffusion Barriers in Metallization,” IITC Conference Report, 2002, 3 Pages.
Elam et al, “Nucleation and Growth During Tungsten Atomic Layer Deposition on SiO2Surfaces,” Thin Solid Films, 2001, 13 Pages.
Collins et al., “Pulsed Deposition of Ultra Thin Tungsten for Plugfill of High Aspect Ratio Contacts,” Presentation made at Semicon Korea 2003, Jan. 21, 2003, 9 pages.
Collins, et al., “Pulsed Deposition of Ultra Thin Tungsten for Plugfill of High Aspect Ratio Contacts,” Semiconductor Equipment and Materials International, Semicon Korea, Jan. 21, 2003, 3 pages.
Lee et al., Pulsed Deposition of Ultra Thin Tungsten and its Application for Plugfill of High Aspect Ratio Contacts, Abstract, Jan. 21, 2003, 1 page.
U.S. Office Action mailed Jul. 12, 2005, from U.S. Appl. No. 10/815,560.
U.S. Office Action mailed Jul. 17, 2002, from U.S. Appl. No. 09/975,074.
U.S. Office Action mailed Feb. 8, 2005, from U.S. Appl. No. 10/649,351.
U.S. Office Action mailed Jul. 14, 2005, from U.S. Appl. No. 10/649,351.
Presentation by Inventor James Fair: “Chemical Vapor Deposition of Refractory Metal Silicides,” 27 Pages, 1983.
Saito et al., “A Novel Copper Interconnection Technology Using Self Aligned Metal Capping Method,” IEEE, 3 Pages, 2001.
U.S. Office Action mailed Jun. 22, 2004, from U.S. Appl. No. 10/435,010.
U.S. Office Action mailed Mar. 23, 2005, from U.S. Appl. No. 10/690,492.
U.S. Office Action mailed Nov. 23, 2005, from U.S. Appl. No. 10/984,126.
Chan et al., “Methods for Growing Low-Resistivity Tungsten Film”, Novellus Systems, Inc., filed Nov. 1, 2005, U.S. Appl. No. 11/265,531, pp. 1-35.
Levy et al., “Deposition of Tungsten Nitride”, Novellus Systems, Inc., filed Dec. 16, 2005, U.S. Appl. No. 11/305,368, pp. 1-39.
U.S. Office Action mailed Dec. 28, 2005, from U.S. Appl. No. 10/815,560.
U.S. Office Action mailed Dec. 30, 2005, from U.S. Appl. No. 10/649,351.
Wongsenakhum et al., “Reducing Silicon Attack

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Methods for forming all tungsten contacts and lines does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Methods for forming all tungsten contacts and lines, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Methods for forming all tungsten contacts and lines will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4308065

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.