Method to remove fluorine residues from bond pads

Adhesive bonding and miscellaneous chemical manufacture – Delaminating processes adapted for specified product – Delaminating in preparation for post processing recycling step

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156651, 156652, 156643, 156646, 134 1, 20419235, H01L 2100

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active

053804015

ABSTRACT:
The process of the present invention comprises the addition of an adequate amount of argon gas in a dry etch system to clear bond pads of residual contaminants which form an undesired oxide coating on the bond pads. Carbon dioxide may be used as a carrier gas along with the argon gas. The process of the present invention preferably takes place in situ, following the silicon nitride pad etch in which fluorine-containing chemicals are used to form the bond pads.

REFERENCES:
patent: 4981550 (1991-01-01), Huttemann et al.
patent: 5202579 (1993-04-01), Fujii et al.
J. F. Graves, W. Gurany, "Reliability Effects of Fluorine Contamination of Aluminum Bonding Pads on Semiconductor Chips", Solid State Technology, Oct. 1983, pp. 227-232.
Dusan Grman, Roland Hauert, Egon Hollander, Markus Amstutz, "Surface Analysis of Fluorine Contamination on Microchip Bond Pads", Solid State Technology, Feb. 1992, pp. 43-47.
J. H. Thomas, III, C. E. Bryson, III, T. R. Pampalone, "X-ray Photoelectron Spectroscopy and Surface Charge Build-up Used to Study Residue on Aluminum Contacts on Integrated Circuits", Surface and Interface Analysis, vol. 14, pp. 39-45, 1989.
R. Jay Ritchie, D. Marshall Andrews, "CF.sub.4 /O.sub.2 Plasma Accelerated Aluminum Metallization Corrosion in Plastic Encapsulated ICs in the Presence of Contaminated Die Attach Epoxies", 1981, pp. 88-92.
T. J. Chuang, H. F. Winters, J. W. Coburn, "An XPS and Auger Investigation of CF.sub.3 +Ion Bombardment of Silicon", North-Holland Publishing Company, 1978, pp. 515-531.
T. Valand, G. Nilsson, "The Influence of F-Ions on the Electrochemical Reactions on Oxide-Covered Al", Corrosion Science, 1977, vol. 17, pp. 449-459.
R. B. Comizzoli, R. P. Frankenthal, P. C. Milner, J. D. Sinclair, "Corrosion of Electronic Materials and Devices", Oct. 1986, pp. 340-345.

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