Method of selectively depositing tungsten upon a semiconductor s

Coating processes – Electrical product produced – Metal coating

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427253, 427255, 4272551, 156646, 156664, 437192, 437228, B05D 512, C23C 1600

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048045608

ABSTRACT:
A method of selectively depositing tungsten upon a silicon semiconductor substrate. A silicon substrate is coated with a masking film of PSG or SiO.sub.2 that is patterned to provide an opening for forming an electrode or wiring. On a portion of the substrate in the opening, a layer of tungsten having a thickness of approximately 2000 .ANG. is deposited by a CVD method from an atomosphere containing a gaseous mixture of WF.sub.6 and H.sub.2 . During this processing, tungsten nucleuses deposit on the surface of the masking film as well. Before such nucleuses form a film, the deposition processing is discontinued and H.sub.2 gas is fed into the CVD apparatus to produce HF, which etches the surface of the masking film, and thus tungsten nucleuses are removed. The deposition and removal steps are repeated several times until the height of the deposited tungsten and the thickness of the masking film are essentially equal to present a flat surface. Aluminum film is deposited on the flat surface and patterned by lithography. The flat aluminum deposition allows fabrication of accurate and reliable wirings and facilitates production of VLSI of sub-micron order.

REFERENCES:
patent: 4404235 (1983-09-01), Tarng et al.
patent: 4412119 (1983-10-01), Komatsu et al.
patent: 4517225 (1985-05-01), Broadbent
patent: 4552783 (1985-11-01), Stoll et al.

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