Method of preventing polymer scale deposition and polymer scale

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymerizing in reactor of specified material – or in reactor...

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526213, 526225, 5263171, 422131, C08F 200, C08F 1406, C08F 200644

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active

052624978

ABSTRACT:
Polymer scale deposition from a polymerization medium in which a monomer having an ethylenic double bond is polymerized, is prevented by conducting the polymerization in a polymerization vessel having a coating by applying a liquid comprising (A) an organic compound containing at least one member selected from the group consisting of a sulfonic acid group and a carboxylic acid group and having a molecular weight of 1000 or less and (B) a water-insoluble compound having an absorption band in the visible light range of 540 to 750 nm, the compounds (A) and (B) having been dissolved or dispersed in (C) an ester-based organic solvent, and having a pH of 3 or less; to the inner wall surfaces of said polymerization vessel. Polymer scale can be effectively prevented and polymeric products are barely colored.

REFERENCES:
patent: 4539230 (1985-09-01), Shimizu et al.

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