Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymerizing in reactor of specified material – or in reactor...
Patent
1992-06-05
1993-11-16
Schofer, Joseph L.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymerizing in reactor of specified material, or in reactor...
526213, 526225, 5263171, 422131, C08F 200, C08F 1406, C08F 200644
Patent
active
052624978
ABSTRACT:
Polymer scale deposition from a polymerization medium in which a monomer having an ethylenic double bond is polymerized, is prevented by conducting the polymerization in a polymerization vessel having a coating by applying a liquid comprising (A) an organic compound containing at least one member selected from the group consisting of a sulfonic acid group and a carboxylic acid group and having a molecular weight of 1000 or less and (B) a water-insoluble compound having an absorption band in the visible light range of 540 to 750 nm, the compounds (A) and (B) having been dissolved or dispersed in (C) an ester-based organic solvent, and having a pH of 3 or less; to the inner wall surfaces of said polymerization vessel. Polymer scale can be effectively prevented and polymeric products are barely colored.
REFERENCES:
patent: 4539230 (1985-09-01), Shimizu et al.
Ueno Susumu
Usuki Masahiro
Watanabe Mikio
Schofer Joseph L.
Shin-Etsu Chemical Co. , Ltd.
Weber Tom
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