Method of photolithography using super-resolution near-field...

Radiation imagery chemistry: process – composition – or product th – Imaging affecting physical property of radiation sensitive... – Making electrical device

Reexamination Certificate

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Details

C430S320000, C430S321000, C430S005000, C430S945000, C430S024000, C430S270130, C369S283000, C369S284000, C369S286000

Reexamination Certificate

active

06506543

ABSTRACT:

CROSS-REFERENCE TO RELATED APPLICATION
This application claims the priority benefit of Taiwan application serial no. 89114791, filed Jul. 24, 2000.
BACKGROUND OF THE INVENTION
1. Field of the Invention
The invention relates in general to a method of photolithography using super-resolution near-field structure. More particularly, this invention relates to a method of photolithography using super-resolution near-field structure to form a pattern with a smaller line width on a photoresist layer.
2. Description of the Related Art
Photolithography process is one of the most crucial steps in semiconductor fabrication process. Through photolithography, the layout of the integrated circuit can be transferred into the semiconductor chip. Typically, a pattern is designed on a photomask. Via exposure and etching processes, the pattern is transferred from the photomask to the photoresist layer with a certain proportion.
Referring to
FIG. 1
to
FIG. 4
, a conventional photolithography process to pattern dimensions and positions of a metal line on a semiconductor chip is shown. In
FIG. 1
, a semiconductor chip
10
comprises a substrate
22
and a photoresist layer
24
formed on the substrate
22
. The substrate
22
further comprises a silicon substrate
12
, doped regions
14
on the silicon substrate
12
, an insulating layer
16
formed of silicon oxide compound on the silicon substrate
12
. Contact plugs
18
are formed in the insulating layer
16
to electrical connect the doped regions
18
and a metal layer
20
formed on the insulating layer
16
.
A positive or negative photoresist layer
24
is formed is formed on the metal layer
20
. When a positive photoresist layer is used, during the photochemical transformation of the exposure process, a light beam penetrates through the photomask pattern to be incident onto the photoresist layer
24
. The portion of the photoresist layer which has not been incident by the light beam is remained by development and cleaning process, while the portion of the photoresist layer which has exposed is removed. A hard mask with the identical pattern on the photomask is thus formed on the semiconductor chip
22
. In contrast, if a negative photoresist layer is in use, the exposed portion is to be remained, while the portion which has not be exposed is to be removed during the subsequent development and cleaning process. In this conventional method illustrated in
FIG. 1
to
FIG. 4
, a positive photoresist layer is used as an example.
In
FIG. 2
, a photomask
30
including a transparent glass or quartz substrate
32
is provided. Non-transparent chromium pattern
34
are formed on the substrate
32
. After the pattern is formed, an exposure step is performed on the photoresist layer
24
using the photomask
30
. The semiconductor chip
10
is then disposed in a developer to perform a development step. Referring to
FIG. 3
, a top view of the semiconductor chip
10
is shown. After the development step, several cleaning steps are required to remove the developer and the resolved positive photoresist layer
24
on the semiconductor chip
10
. As shown in
FIG. 4
, after the cleaning steps, an etching step is performed using the remaining photoresist layer
26
as a hard mask to remove the metal layer
24
which has not been covered by the remaining photoresist layer
26
until the insulating layer
16
is exposed. The remaining photoresist layer
26
is then removed, followed by formation of the patterned metal lines
28
in contact with the metal plugs
18
.
As the complexity and integration keep increasing, the pattern
32
on the photomask
30
has to be designed smaller and smaller. However, while transferring the pattern, the critical dimension of the pattern transferred by exposure is restricted to the resolution limit of the optical exposure tool. As a result, while performing exposure to transfer a high density photomask pattern
34
into the photoresist pattern
26
on the semiconductor chip
10
, optical proximity effect is easily to occur. The photoresist layer is thus over exposed or under exposed to cause resolution loss. The critical dimension of the pattern is consequently shrunk result in a transferred photoresist pattern that is not identical to the photomask pattern. The device performance is thus seriously affected.
SUMMARY OF THE INVENTION
The invention provides a method of photolithography using super-resolution near-field structure to form a pattern with a narrow line width.
A method of photolithography using a super-resolution near-field structure is provided. The method of photolithography is applied to pattern a photoresist pattern on a semiconductor chip. The semiconductor chip comprises a substrate and a photoresist layer on the substrate. A super-resolution near-field structure is formed on the photoresist layer. The super-resolution near-field structure comprises a first dielectric layer, a second dielectric layer and an active layer sandwiched between the first and the second dielectric layer. A light beam is incident on the semiconductor chip. The light beam transmits through the super-resolution near-field structure to expose the photoresist layer. Transmitting through the super-resolution near-field structure, the light intensity of the light beam is increased, while the aperture thereof is reduced.
In the invention, using the super-resolution near-field structure, the aperture of the exposure light source can be reduced, and the light intensity can be increased to breakthrough the resolution limit of a machine. Thus, to form a photoresist layer with a line width breaking the resolution limit is possible. By adjusting the thickness of the thin film of the super-resolution near-field structure, the aperture of the exposure light source can be shrunk, the dimension of the exposed spot on the photoresist layer is no more restricted by the resolution limit of the exposure machine.
Both the foregoing general description and the following detailed description are exemplary and explanatory only and are not restrictive of the invention, as claimed.


REFERENCES:
patent: 6087067 (2000-07-01), Kato et al.
patent: 6254966 (2001-07-01), Kondo
patent: 6285652 (2001-09-01), Tsai et al.

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