Method of manufacturing semiconductor device

Semiconductor device manufacturing: process – Introduction of conductivity modifying dopant into... – Ion implantation of dopant into semiconductor region

Reexamination Certificate

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C438S527000

Reexamination Certificate

active

06475887

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates generally to semiconductor devices and a method of manufacturing the same and, more particularly, to a semiconductor device having an MOS (Metal-Oxide-Semiconductor) transistor and a manufacturing method thereof.
2. Description of the Background Art
Conventionally, a semiconductor device including a P channel MOS transistor is known as one of semiconductor devices.
FIG. 40
is a cross-sectional view showing a conventional semiconductor device including a P channel MOS transistor. Referring to
FIG. 40
, an isolation oxide film
102
is formed at a predetermined region on a main surface of an N type silicon substrate
101
for element isolation in the conventional semiconductor device. On an active region surrounded by isolation oxide film
102
, P type source/drain regions
106
a
and
106
b
are formed spaced apart by a predetermined distance from each other to sandwich a channel region
110
. On channel region
110
, a gate electrode
104
is formed with a gate oxide film
103
posed therebetween. Sidewall oxide films
105
are formed at both sidewall portions of gate electrode
104
.
A P channel MOS transistor is formed of P type source/drain regions
106
a
,
106
b
, gate oxide film
103
and gate electrode
104
. Gate electrode
104
is formed of polycrystalline silicon including P type impurities such as boron (B) and has a thickness of about 2000 Å.
FIGS. 41-46
are cross-sectional views showing a method of manufacturing the conventional semiconductor device shown in FIG.
40
. Referring to
FIGS. 40-46
, a process of manufacturing the conventional semiconductor device will be described.
At first, as shown in
FIG. 41
, an isolation oxide film
102
is formed using LOCOS (LOCal Oxidation of Silicon) method at a predetermined region on the main surface of N type silicon substrate
101
. A silicon oxide film (not shown) and a non-doped polycrystalline silicon film (not shown) having a thickness of about 2000 Å are formed all over the surface and then patterned, so that a gate oxide film
103
formed of the silicon oxide film and a gate electrode
104
formed of the non-doped polycrystalline silicon film are formed.
Next, as shown in
FIG. 42
, a resist
111
is formed using photolithography to cover a region except for gate electrode
104
. Boron is ion-implanted into gate electrode
104
using resist
111
as a mask. After that resist
111
is removed. Next as shown in
FIG. 43
, heat treatment at a temperature in the range of about 800° C. to 1000° C. is carried out for thirty minutes to activate impurities (boron) ion-implanted into gate electrode
104
.
As shown in
FIG. 44
, after a silicon oxide film (not shown) is formed all over the surface, a sidewall oxide film
105
is formed at both sidewall portions of gate electrode
104
by anisotropic etching.
As shown in
FIG. 45
, a resist
112
is formed on gate electrode
104
using photolithography. After that, as shown in
FIG. 46
, P type impurities such as boron are ion-implanted into silicon substrate
101
using resist
112
, sidewall oxide film
105
and isolation oxide film
102
as a mask. Thus, P type ion-implanted regions
107
a
and
107
b
are formed.
After that, resist
112
is removed. Then, boron introduced into ion-implanted regions
107
a
and
107
b
is electrically activated by heat treatment at a temperature of 800° C. for about thirty minutes. Thus, impurity diffusion regions (source/drain regions)
106
a
and
106
b
are formed as shown in FIG.
40
. In this manner, a semiconductor device having a conventional P channel MOS transistor has been formed.
In the conventional semiconductor device described above, impurity is undesirably redistributed by the heat treatment in activating the impurity introduced into P type impurity implanted regions
107
a
and
107
b
shown in FIG.
46
. More specifically, impurity introduced into P type impurity implanted regions
107
a
and
107
b
diffuses in all directions inside silicon substrate
101
by heat treatment. As a result, P type impurity diffusion regions (source/drain regions)
106
a
and
106
b
(see
FIG. 40
) which are larger than P type impurity implanted regions
107
a
and
107
b
are formed (see FIG.
46
).
FIG. 47
is a cross-sectional view showing a problem of the conventional semiconductor device. Referring to
FIG. 47
, as the size of P type source/drain regions
106
a
and
106
b
becomes larger by impurity diffusion caused by heat treatment, channel length L is reduced. Thus, so called punch through phenomenon occurs in which current cannot be controlled by the gate voltage because a depletion layer in the vicinity of one of the source/drain regions
106
a
and
106
b
, for example, spreads to the other region thereof. This punch through phenomenon considerably appears when an element is miniaturized.
Another problem is that by heat treatment in activating P type impurity in a gate electrode
104
, the P type impurity (boron) passes through a gate oxide film
103
to diffuse into a channel region
110
. When the P type impurity in gate electrode
104
diffuses into channel region
110
, there occurs a problem that threshold voltage the MOS transistor changes.
SUMMARY OF THE INVENTION
One object of the invention is to effectively prevent punch through phenomenon in a semiconductor device.
Another object is to effectively prevent the change of threshold voltage caused by diffusion of impurity in the gate electrode into the channel region in the semiconductor device.
Still another object is to effectively suppress the impurity diffusion caused by heat treatment in forming source/drain regions in a method of manufacturing a semiconductor device.
A further object of the invention is to effectively prevent the diffusion of impurities in the gate electrode into the channel region caused by heat treatment for activation thereof in the method of manufacturing the semiconductor device.
According to the first aspect of the present invention, a semiconductor device includes a semiconductor region of a first conductivity type having a main surface, a pair of source/drain regions of a second conductivity type having a predetermined junction depth formed spaced apart by a predetermined distance from each other to sandwich a channel region on the main surface of the semiconductor region, an implanted layer having depth equal to or greater than the junction depth of the source/drain regions, formed along the entire junction region of the source/drain regions and including a material selected from the group consisting of nitrogen, fluorine, argon, oxygen and carbon, and a gate electrode formed on the channel region with a gate insulation layer posed therebetween. Preferably, the implanted layer described above is formed to have depth greater than the junction depth of the source/drain regions and to cover the source/drain regions.
In the semiconductor device, since the implanted layer having the depth equal to or greater than the junction depth of the source/drain regions is formed along the entire junction region of the source/drain regions, impurity diffusion caused by heat treatment in forming the source/drain regions can be effectively prevented. Thus, unlike the conventional device, reduction of the channel length caused by the impurity diffusion is prevented, effectively reducing the punch through phenomenon. Note that if the implanted layer described above is formed to have the depth greater than the junction depth of source/drain regions and to cover the source/drain regions, the impurity diffusions caused by heat treatment in the formation of the source/drain regions is suppressed more effectively.
According to another aspect of the present invention, a semiconductor device includes a semiconductor region of a first conductivity type having a main surface, a pair of source/drain regions of a second conductivity type formed with a predetermined distance therebetween to sandwich a channel region on the main surface of the semiconductor device, and a gat

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