Method of manufacturing Group III nitride crystal substrate,...

Semiconductor device manufacturing: process – Chemical etching – Combined with the removal of material by nonchemical means

Reexamination Certificate

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C117S073000, C117S077000

Reexamination Certificate

active

07125801

ABSTRACT:
The present invention provides a Group III nitride crystal substrate whose surface has concavities and convexities reduced in size. The surfaces with concavities and convexities, such as hillocks, pits and facets, of Group III nitride crystals are brought into contact with a melt and thereby the surfaces are subjected to meltback etching or mechanochemical polishing. The melt includes at least one of alkali metal and alkaline-earth metal. Thus a Group III nitride crystal substrate that has reduced strain and a reduced number of defects, which are caused through the processing, and is excellent in surface flatness is manufactured. Furthermore, by the use of the Group III nitride crystal substrate of the present invention, for instance, semiconductor devices of high performance can be obtained.

REFERENCES:
patent: 2002/0037599 (2002-03-01), Ishida et al.
patent: 2004/0003495 (2004-01-01), Xu
patent: 2002-293696 (2002-10-01), None
patent: 2004013385 (2004-02-01), None
F.Kawamura et al., “Growth of Transpatent Large Size GaN Single Crystal with Low Dislocations Using Alkali Metal-based Flux”, Japanese Association for Crystal Growth, vol. 30, No. 2, pp. 96-103 (2003).
F.A. Ponce et al., “Homoepitaxy of GaN on polished bulk single crystal by metalorganic chemical vapor desposition”, Appl. Phys. Let., vol. 68, No. 7 pp. 917-919 (1996).
Y.Kaneko et al., “Melt-Back Etching of GaN”, Solid-state Electrons, vol. 41, No. 2, pp. 295-298 (1997).

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