Method of forming gate oxide layer in semiconductor devices

Semiconductor device manufacturing: process – Making field effect device having pair of active regions...

Reexamination Certificate

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C134S002000, C134S003000

Reexamination Certificate

active

06878575

ABSTRACT:
Methods of preparing improved semiconductor substrates having gate oxide layers formed thereon, and use of such substrates in fabricating improved semiconductor devices, are disclosed. The methods include a first step of performing a cleaning process for removing a natural oxide layer formed on a semiconductor substrate and also for removing an oxide layer generated by the removal of the natural oxide layer; a second step of executing a hydrogen annealing process to form a hydrogen passivation layer and for further reducing a surface roughness of the semiconductor substrate completed in the cleaning process; a third step of forming a gate oxide layer thereon; a fourth step of performing a nitridation process on the gate oxide layer to prevent the semiconductor substrate from a permeation of ions during a subsequent gate electrode formation step; and, a fifth step of performing a subsequent thermal process to stabilize a surface of the gate oxide layer, thereby improving a defect rate of the device caused in forming the gate oxide layer.

REFERENCES:
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patent: 6008128 (1999-12-01), Habuka et al.
patent: 6124218 (2000-09-01), Hwang
patent: 6127282 (2000-10-01), Lopatin
patent: 6391796 (2002-05-01), Akiyama et al.
patent: 20020036324 (2002-03-01), Houston et al.

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