Method of forming gate electrode in semiconductor device

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – Insulated gate formation

Reexamination Certificate

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C438S592000

Reexamination Certificate

active

06333250

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a method of manufacturing a semiconductor device, and more particularly to a method of forming a tungsten gate electrode.
2. Description of the Related Art
In general, a polysilicon layer is used for a gate electrode material of a MOSFET. However, as high integration of a semiconductor device, the line width of the gate electrode is significantly reduced. Therefore, in case of a polysilicon gate electrode, it is difficult to obtain low resistivity required for the high integration device. Accordingly, a tungsten layer has been researched as the gate electrode material, recently.
In case of a tungsten gate electrode, gate re-oxidation process is generally performed after forming a tungsten gate electrode, for improving the reliability of a gate insulating layer. However, when performing the gate re-oxidation process, the side wall of a tungsten layer
5
is excessively oxidized due to its fast oxidation rate, to occur abnormal oxidation of the tungsten layer
5
, as shown in
FIG. 1
, thereby deteriorating properties and reliability of a device. In
FIG. 1
, reference numbers
1
,
2
,
3
and
4
indicate a semiconductor substrate, a gate oxide layer, a polysilicon layer and a diffusion barrier layer, respectively. Furthermore, reference numbers
6
and
7
indicate a mask pattern used for etch barrier and a thermal oxidation layer grown by abnormal oxidation, respectively.
To solve the above problem, a method of forming a tungsten gate electrode using a spacer, is suggested. Referring to
FIG. 2
when performing etch process to form a gate electrode, the tungsten layer
5
and the diffusion barrier layer
4
are etched and a spacer
8
is then formed on the side wall of the etched tungsten layer
5
and diffusion barrier layer
4
. Therefore, when performing subsequent gate re-oxidation process, abnormal oxidation is not occurred on side wall of the tungsten layer
5
.
Thereafter, as not shown in
FIG. 2
, the polysilicon layer
3
and the gate oxide layer
2
are etched to form a gate electrode. Next, LDD ion implantation and gate re-oxidation processes are performed, respectively.
As described above, when performing gate re-oxidation process, abnormal oxidation is not occurred on side of the tungsten layer
5
by the spacer
8
. However, since the width of the gate electrode increases due to the spacer
6
, it is difficult to apply high integration semiconductor device required for a gate electrode with fine line width.
SUMMARY OF THE INVENTION
It is therefore an object of the present invention to provide a method of forming a gate electrode in a semiconductor device which can prevent abnormal oxidation of a tungsten layer without increasing the line width of the gate electrode by etching a tungsten layer and a diffusion barrier layer to the width of a spacer prior to forming the spacer, for solving the problems in the conventional art.
To accomplish this above object, a method of forming a gate electrode in a semiconductor device according to the present invention includes steps of: forming a gate oxide layer, a polysilicon layer, a diffusion barrier layer, a metal layer and a mask layer on a semiconductor substrate, in sequence; patterning the mask layer, the metal layer and the diffusion barrier layer to the first width; patterning the mask layer, the metal layer and the diffusion barrier layer having the first width to a second width by wet etching; forming a spacer on the side walls of the mask layer, the metal layer and the diffusion barrier layer having the second width; and patterning the polysilicon layer and the gate oxide layer using the mask layer and the spacer as an etch barrier.
According to the present invention, since a spacer is formed on the sides a metal layer and a diffusion barrier layer after etching the metal layer and the diffusion barrier layer to the width of the spacer, it is possible to obtain a gate electrode with fine line width and abnormal oxidation is not occurred on the sides of the metal layer.


REFERENCES:
patent: 4404732 (1983-09-01), Andrade
patent: 4740826 (1988-04-01), Chatterjee
patent: 4929567 (1990-05-01), Park et al.
patent: 5071788 (1991-12-01), Joshi
patent: 5112765 (1992-05-01), Cederbaum et al.
patent: 5116774 (1992-05-01), Huang et al.
patent: 5212400 (1993-05-01), Joshi
patent: 5599725 (1997-02-01), Dorleans et al.
patent: 5633522 (1997-05-01), Dorleans et al.
patent: 5688706 (1997-11-01), Tseng
patent: 5789312 (1998-08-01), Buchanan et al.
patent: 5858867 (1999-01-01), Hsia et al.
patent: 5925918 (1999-07-01), Wu et al.
patent: 5998290 (1999-12-01), Wu et al.
patent: 6037228 (2000-03-01), Hsu
patent: 6075274 (2000-06-01), Wu et al.
patent: 6107171 (2000-08-01), Tsai
patent: 6165883 (2000-12-01), Hiura
patent: 6235621 (2001-05-01), Jung et al.
patent: 6236093 (2001-05-01), Hiura
patent: 55030867 (1980-03-01), None
patent: 60015920 (1985-01-01), None
patent: 61241974 (1986-10-01), None
patent: 01125985 (1989-05-01), None
patent: 01175257 (1989-07-01), None
patent: 01187871 (1989-07-01), None
patent: 01207971 (1989-08-01), None
patent: 01207972 (1989-08-01), None
patent: 01207973 (1989-08-01), None
patent: 01251758 (1989-10-01), None
patent: 02007552 (1990-01-01), None
patent: 02026074 (1990-01-01), None
patent: 02077162 (1990-03-01), None
patent: 02129917 (1990-05-01), None
patent: 04336468 (1992-11-01), None
patent: 07263680 (1995-10-01), None
patent: 10135452 (1998-05-01), None

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