Method of forming a self-aligned contact hole on a...

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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Details

C438S643000, C438S637000, C438S258000

Reexamination Certificate

active

06306760

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a method of forming a self-aligned contact hole on a semiconductor wafer, and more particularly, to a method of forming a self-aligned contact hole with a large contact area on a semiconductor wafer.
2. Description of the Prior Art
For years, the self-aligned contact (SAC) etching technology has been widely used in the manufacturing processes for dynamic random access memory (DRAM) and embedded dynamic random access memory (e-DRAM). It is used, for example, when making a contact hole in a DRAM chip through which a memory cell on the DRAM chip connects with a bit line. A small amount of misalignment can be tolerated when using the SAC technology in the prior art method of forming a self-aligned contact hole. However, owing to the increasing integration of semiconductor devices, and the limitation of the width of the spacers of a metal-oxide-semiconductor (MOS) transistor, the prior art method of forming a self-aligned contact hole has a disadvantage that the decreasing contact area results in an increased resistivity of the contact plug.
Please refer to
FIG. 1
to FIG.
5
.
FIG. 1
to
FIG. 5
are cross-sectional diagrams of the prior art method of forming a self-aligned contact hole on a semiconductor wafer. Please refer to
FIG. 1. A
cross-sectional view of a portion of a silicon substrate
12
with a partially completed DRAM cell is shown. A semiconductor wafer comprises the silicon substrate
12
and a shallow, dielectric-filled trench
14
located on the surface of the silicon substrate
12
that isolates the individual device regions. The silicon substrate
12
comprises an array area
20
that comprises an array of memory cells of dynamic random access memory, and a periphery area
30
located on the substrate
12
comprising a control circuit of the DRAM. The array of memory cells in the array area
20
comprises a first gate electrode
16
, and a second gate electrode
16
adjacent to the first gate electrode
16
. The control circuit in the periphery area
30
comprises at least a third gate electrode
18
.
As shown in
FIG. 2
, in the prior art method the lightly doped drain (LDD) areas
22
that are used to prevent short channel effects are first formed adjacent to the gate electrodes
16
,
18
. Usually, the gate electrodes
16
,
18
are used as part of the implantation mask, and N-type dopant species such as arsenic or phosphorus are implanted into the substrate. Next, a silicon dioxide buffer oxide layer
24
, and a silicon nitride layer (not shown in
FIG. 2
) are sequentially formed on the silicon substrate
12
using a chemical vapor deposition (CVD) process. The buffer oxide layer
24
serves to reduce the thermal stress of the silicon nitride layer. The silicon nitride layer is used to form subsequent spacers
25
. The preferred thickness of the buffer oxide layer
24
is typically between 100 to 200 Angstroms. As shown in
FIG. 3
, after depositing the buffer oxide layer
24
and the silicon nitride layer, an anisotropic dry etching process is used to form the spacers
25
on the walls of opposite sides of the gate electrodes
16
,
18
.
Referring next to the
FIG. 4
, an ion implantation process follows to form the source
27
and drain
28
in the periphery area
30
, and a subsequent annealing process is used to restore the lattice structure which is damaged by the incident atoms and electrons during the implantation process. Then, a second silicon nitride layer
29
, acting as the salicide block mask (SAB) in the formation of a salicide layer
26
, is formed over the array area
20
by a CVD process. Furthermore, in order to reduce the contact resistance to the source
27
and drain
28
, a silicidation process is performed on the surface of the source
27
and drain
28
to form a silicide layer, wherein titanium and cobalt are typically used as the metal source in the silicidation process.
Referring next to the
FIG. 5
, an inter-poly dielectric layer
32
is formed on the surface of the semiconductor wafer
10
by a CVD process. Then, a photoresist layer (not shown) is formed on at he surface of the semiconductor wafer
10
, and a photo-lithographic process is performed to define the location of the self-aligned contact hole. Finally, a wet etching process is performed to remove the photoresist layer over the contact hole and a self-aligned contact dry etching process is used to complete the self-aligned contact hole
34
.
Referring still to
FIG. 5
, damage to the buffer oxide layer
24
is observed after the self-aligned contact etching process in the prior art. The inter-poly dielectric layer
32
and the buffer oxide layer
24
are both composed of silicon dioxide. Hence, the plasma etches both of the layers during the self-aligned contact etching process.
Please refer to FIG.
6
.
FIG. 6
is a cross-sectional diagram of the prior art method of forming a polysilicon plug in the self-aligned contact hole. After completing the self-aligned contact hole
34
, a polysilicon plug is formed in the contact hole
34
so as to make electrical connections between the circuits and the semiconductor regions. However, the damage to the buffer oxide layer
24
adjacent to the gate electrodes
16
,
18
results in contact between the gate and the plug, thereby forming a short circuit after the formation of the polysilicon plug.
As integration of semiconductor devices and the density of memory cells in and on a DRAM chip increase, the contact area
36
at the bottom of the self-aligned contact hole
34
shrinks. A small contact area may result in an undesirable high resistivity, which increases the signal transfer time and energy consumption of a semiconductor device. In order to reduce the contact plug resistivity, it is desirable to make the contact area as large as possible for the DRAM fabrication process.
Unfortunately, the contact area
36
is limited by the thickness of the spacers
25
in the prior art. As shown in
FIG. 5
, the thickness of the spacers
25
in the periphery area
30
is the same as the spacers
25
in the array area
20
because they are all formed at the same time. The width of the lightly doped drain areas
22
with respect to the thickness of the spacers
25
will significantly influence the electrical properties of a metal-oxide-semiconductor (MOS) transistor in the periphery area
30
. Thin spacers result in narrow lightly doped drain areas, which can cause serious thermal electron problems in the MOS transistor. Consequently, it is impossible to increase the contact area
36
by reducing the thickness of the spacers
25
in the array area
20
in the prior art. A solution to this problem is of considerable importance.
The main disadvantage of the prior art method of forming a self-aligned contact hole is that it cannot provide sufficient contact area
36
to the source
27
and drain
28
in the array area
20
. This results in a high resistivity that reduces the performance of the semiconductor device.
SUMMARY OF THE INVENTION
It is therefore a primary objective of the present invention to provide a method of forming a self-aligned contact hole on a semiconductor wafer to solve the above mentioned problem.
In a preferred embodiment, the present invention relates to a method of forming a self-aligned contact hole on a semiconductor wafer. The semiconductor wafer comprises a substrate, an array area comprising all of the memory cells of a DRAM and a periphery area comprising a control circuit of a DRAM. The array area and the periphery area are both located on the surface of the substrate. The array of memory cells in the array area comprises a first gate electrode and a second gate electrode adjacent to the first gate electrode. The control circuit in the periphery area comprises at least a third gate electrode. The method comprises:
forming a first doped area over each of two opposite sides of each gate electrode;
forming a first spacer on a wall of each of the two opposite sides of the third gate electrode in the periphery area; and
form

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