Method of forming a metal layer over patterned dielectric by...

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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C438S677000, C438S687000

Reexamination Certificate

active

06951816

ABSTRACT:
A metal layer is formed by means of an electroless plating process, wherein a surface region of an underlying material is catalytically activated in that a catalyst is deposited or incorporated by CVD, PVD or ALD during and/or after the deposition of the underlying material. In this way, superior metal seed layers may be formed even in high aspect ratio vias of metallization structures.

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Shacham-Diamand et al., “Electroless copper deposition for ULSI,”Thin Solid Films, 262:93-103, 1995.
Lin et al., “Interfacial mechanism studies of electroless plated CU films on a-Ta:N layers catalyzed by PIII,”J. Vac. Sci. Technol., 20:733-40, 2002.

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