Method of forming a metal gate structure with tuning of work...

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – Insulated gate formation

Reexamination Certificate

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Reexamination Certificate

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07071086

ABSTRACT:
A method for forming a semiconductor structure having a metal gate with a controlled work function includes the step of forming a precursor having a substrate with active regions separated by a channel, a temporary gate over the channel and within a dielectric layer. The temporary gate is removed to form a recess with a bottom and sidewalls in the dielectric layer. A non-silicon containing metal layer is deposited in the recess. Silicon is incorporated into the metal layer and a metal is deposited on the metal layer. The incorporation of the silicon is achieved by silane treatments that are performed before, after or both before and after the depositing of the metal layer. The amount of silicon incorporated into the metal layer controls the work function of the metal gate that is formed.

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patent: P2001-77355 (2001-02-01), None
Hitoshi Wakabayashi et al., “A Dual-Metal Gate CMOS Technology Using Nitrogen-Concentration-Controlled TiNx Film”, IEEE Transactions On Electron Devices, vol. 48, No. 10, Oct. 2001, pp. 2363-2369.
James Pan et al., “A Low-Temperature Metal-Doping Technique for Engineering the Gate Electrode of Replacement Metal Gate CMOS Transistors”, IEEE Electron Device Letters, vol. 24, No. 9, Sep. 2003, pp. 547549.

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