Method of continuous production of polyalkylbiphenyls

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire cyclic molecules or entire...

Reexamination Certificate

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C585S464000, C585S467000, C585S716000

Reexamination Certificate

active

10647592

ABSTRACT:
A method of continuously producing polyalkylbiphenyls involves reacting biphenyl and an olefin in the presence of a solid acid catalyst to obtain a reaction mixture containing monoalkylbiphenyls and dialkylbiphenyls, separating a fraction containing biphenyl and at least a part of the monoalkylbiphenyls, circulating the separated fraction to the reactor such that the ratio of biphenyls to monoalkylbiphenyls is designed to be 0.1 or more and is designed to be less than the soluability of biphenyl to monoalkylbiphenyl at a circulation temperature, and recovering polyalkylbiphenyls.

REFERENCES:
patent: 4783567 (1988-11-01), Kocal
patent: 4982037 (1991-01-01), Nakamura et al.
patent: 5817908 (1998-10-01), Mehlberg
patent: 0285280 (1988-10-01), None
patent: 0508835 (1992-10-01), None
patent: 49-80045 (1974-08-01), None
patent: 56-156222 (1981-12-01), None
patent: 03-106833 (1991-05-01), None
patent: 09-040588 (1997-02-01), None

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