Method of bleaching pulp with ozone-chlorine mixtures

Paper making and fiber liberation – Processes of chemical liberation – recovery or purification... – Gas – vapor or mist contact

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162 66, 162 88, 162 89, D21C 912, D21C 9147, D21C 9153, D21C 914

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049023810

ABSTRACT:
Ozone and chlorine are used to bleach cellulosic fibrous material pulp in the production of kraft pulp for paper and paper products, being applied together in a mixture. When the ozone and chlorine are applied simultaneously it is possible to achieve delignification to a greater extent than is possible utilizing chlorine at any level. The total chlorinated ring compounds in the bleach plant effluent are remarkably reduced utilizing the ozone-chlorine mixture, compared to all chlorine, with resulting decrease in the fish toxicity of the bleach plant effluent. Utilizing an O.sub.3 /Cl.sub.2 E.sub.o D bleaching sequence (only three stages) it is possible to obtain pulp with 90 TAPPI Absolute, or greater, brightness.

REFERENCES:
patent: 396325 (1889-01-01), Brin
patent: 1957937 (1934-05-01), Campbell et al.
patent: 4080249 (1978-03-01), Kempf et al.
patent: 4093506 (1978-06-01), Richter
patent: 4372812 (1983-02-01), Phillips et al.
Liebergott et al, "The Use of Ozone in Bleaching and Brightening Wood Pulps", Tappi, Pulp & Paper Seminar, Nov. 1978.
Enz et al, "Oxidative Extraction: An Opportunity of Splitting the Bleach Plant", Tappi, Jun. 1984.
Singh, "Ozone Replaces Chlorine in the First Bleaching Stage", Tappi, vol. 65, No. 2, Feb. 1982.
Berry et al, "Using Oxygen-Alkali Extraction to Simplify the Chlorination Stage", J. Pulp & Paper Science, vol. 12, No. 5; Sep. 1986.

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