Method for vapor deposition of a metal compound film

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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C438S769000, C438S770000, C438S775000

Reexamination Certificate

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06846743

ABSTRACT:
A method for forming a metal compound film includes alternate irradiation of an organometal compound and oxygen or nitrogen radicals to deposit monoatomic layers of the metal compound. The organometal compound includes zirconium, hafnium, lanthanide compounds. The resultant film includes little residual carbon and has excellent film characteristic with respect to leakage current.

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patent: 6511539 (2003-01-01), Raaijmakers
patent: 6521911 (2003-02-01), Parsons et al.
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patent: 6669825 (2003-12-01), Ohmi et al.
H. J. Osten et al. “High-k Gate Dielectrics with Ultra-low Leakage Current Based on Praseodymium Oxide”, IEDM Technical Digests 2000, pp. 653-656 with Abstract.
L. Manchanda et al., “Si-Doped Aluminates for High Temperature Metal-Gate CMOS: Zr-Al-Si-O, A Novel Gate Dielectric for Low Power Applications”, IEDM Technical Digests 2000, pp. 23-26 with Abstract.

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