Specialized metallurgical processes – compositions for use therei – Processes – Free metal or alloy reductant contains magnesium
Patent
1982-12-13
1984-05-01
Meros, Edward J.
Specialized metallurgical processes, compositions for use therei
Processes
Free metal or alloy reductant contains magnesium
75114, 75101R, 423 34, 423 38, C22B 1106
Patent
active
044459351
ABSTRACT:
The method of the present invention is directed to the recovery of silver from spent photographic fixer solutions and for providing an effluent essentially silver-free that is suitable for discharge into commercial sewage systems. The present method involves the steps of introducing the spent photographic fixer solution into an alkaline hypochlorite solution. The oxidizing conditions of the alkaline hypochlorite solution are maintained during the addition of the fixer solution so that the silver ion complexing agents of thiosulfate and sulfite ions are effectively destroyed. Hydrazine monohydrate is then added to the oxidizing solution to form a reducing solution to effect the formation of a precipitate of silver which can be readily removed by filtration or decanting. Experimental tests indicate that greater than 99.99% of the original silver in the spent photographic fixer can be efficiently removed by practicing the present method. Also, the chemical and biological oxygen demand of the remaining effluent is significantly reduced so as to permit the discharge thereof into sewage systems at levels in compliance with federal and state environmental standards.
REFERENCES:
patent: 3594157 (1971-07-01), Hendrickson et al.
Palko Aloysius A.
Posey Franz A.
Esposito Michael F.
Hamel Stephen D.
Larcher Earl L.
Meros Edward J.
Stoll Robert L.
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