Method for the growth of epitaxial metal-insulator-metal-semicon

Metal treatment – Barrier layer stock material – p-n type – With non-semiconductive coating thereon

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148 334, 148 335, 148 336, H01L 2912

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053644689

ABSTRACT:
In one form of the invention, a method for the growth of an epitaxial insulator-metal structure on a semiconductor surface comprising the steps of maintaining the semiconductor surface at a pressure below approximately 1.times.10.sup.-7 mbar, maintaining the semiconductor surface at a substantially fixed first temperature between approximately 25.degree. C. and 400.degree. C., depositing an epitaxial metal layer on the semiconductor surface, adjusting the semiconductor surface to a substantially fixed second temperature between approximately 25.degree. C. and 200.degree. C., starting a deposition of epitaxial CaF.sub.2 on the first metal layer, ramping the second temperature to a third substantially fixed temperature between 200.degree. C. and 500.degree. C. over a time period, maintaining the third temperature until the epitaxial CaF.sub.2 has deposited to a desired thickness, and stopping the deposition of epitaxial CaF.sub.2 on the first metal layer.

REFERENCES:
patent: 4665412 (1987-05-01), Ohkawa et al.
Petroff et al. in "Properties of alluminum epitaxial growth" J. Appl. Phys. vol. 52(12), Dec. 1981, pp. 7317-7320.
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Yamada et al. in "Metallization by ion cluster beam deposition" in IEEE trans. Elec. Dev. vol. ED 34.(5), May 1987, pp. 1018-1025.
Phillips et al. in "Using rapid thermal annealing to improve epitaxial CaF.sub.2 /CoSi.sub.2 /Si(111) structures" in MRS Sym. Proc. vol. 67, 1986, pp. 115-118.
Fauthaur et al. in "Heteroepitaxy of Insulator/metal/silicon structures: CaF.sub.2 /NiSi.sub.2 /Si(111) and CaF.sub.2 /CoSi.sub.2 Si(111)," in Appl. Phys. Letts. vol. 49(2), Jul. 1986, pp. 64-66.
Cho, et al., "Epitaxial Growth of an Al/CaF.sub.2 /Al/Si(111) Structure,"Applied Physics Letters, vol. 61, No. 3, Jul. 20, 1992, pp. 270-272.
Cho, "Low Temperature Epitaxial Growth of Al on Si(111) and CaF.sub.2 (111) Using Molecular Beam Epitaxy," Materials Research Society Symposium Proceedings, vol. 221, 1991, pp. 87-92.
Schowalter, et al., "Growth and Characterization of Single Crystal Insulators on Silicon," Critical Reviews in Solid State and Materials Science, vol. 15, 1988, pp. 367-421.

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