Method for selective removal of hard trench masks

Adhesive bonding and miscellaneous chemical manufacture – Delaminating processes adapted for specified product – Delaminating in preparation for post processing recycling step

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437 67, 437 72, 437 78, B44C 122

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054258456

ABSTRACT:
After trench formation on a semiconductor wafer (14) using a hard trench mask containing a phosphosilicate glass top layer and an underlying thermal oxide layer, the phosphosilicate glass layer may be removed without substantially etching the thermal oxide layer. The wafer temperature is increased to at least 40.degree. C. (36) prior to etching with an HF/H.sub.2 O vapor (40-44).

REFERENCES:
patent: 5047815 (1991-09-01), Yasuhira
patent: 5173152 (1992-12-01), Tanaka
patent: 5231046 (1993-07-01), Tasaka
S. Wolf and R. N. Tauber, "Silicon Processing for the VLSI Era" vol. 1-Process Technology, Lattice Press, 1986, pp. 523-527 and 567.
B. E.Deal, M. A. McNeilly, D. B. Kao and J. M. deLarios, "Vapor-Phase Wafer Cleaning, Oxide Etching and Thin Film Growth", Presented at 1st Intl. Symposium on Cleaning Technology in Semiconductor Device Mfg. Fall Meeting, The Electrochem. Soc. in Hollywood, Fla. Oct./1989.
Man Wong, M. M. Moslehi and R. A. Bowling, "Wafer Temperature Dependence of the Vapor-Phase HF Oxide Etch", J. Electrochem. Soc., vol. 140, No. 1, pp. 205-208, Jan. 1990.
M. Wong, M. M. Moslehi and D. W. Reed, "Characterization of Wafer Cleaning and Oxide Etching Using Vapor-Phase Hydrogen Flouride", J. Electrochem. Soc., vol. 136, No. 6, pp. 1799-1802, Jun. 1991.
M. Wong, D. K. Y. Liu, M. M. Moslehi and D. W. Reed, "Preoxidation Treatment Using HCl/HF Vapor", IEEE Electron Device Letters, vol. 12, No. 8, pp. 425, 426, Aug. 1991.

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