Method for sampling in flameless atomic absorption spectrophotom

Optics: measuring and testing – By dispersed light spectroscopy – With sample excitation

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G01J 330

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042252342

ABSTRACT:
A method of flameless atomic absorption analysis in which an element in a sample is measured by vaporizing the sample in a graphite crucible or cuvette and measuring the absorbance of the atomic vapor at a wavelength characteristic of the element. The method includes the steps of (1) successively introducing a preselected number of aliquots of the same sample into the graphite cuvette, (2) thermally pretreating each sample aliquot upon introduction to remove volatile or decomposable substances therefrom, and (3) vaporizing sample remaining in the cuvette for measurement only after performing the predetermined successive number of sample introduction and thermal pretreatment cycles.

REFERENCES:
patent: 3788752 (1974-01-01), Slavin et al.
"Controlled Atmosphere Discontinuous Semiautomatic Dispenser for Carbon Rod Atomizer"; Sacchetti et al.; Analytical Chemistry, vol. 48#8 Jul. 1976 pp. 1175-1177.

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