Method for promoting aluminum chloride catalyzed isomerization o

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By isomerization

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C07C 524, C07C 528

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043841562

ABSTRACT:
A method is disclosed for promoting isomerization of sym-octahydrophenanthrene (s-OHP) to sym-octahydroanthracene (s-OHA) in the presence of a catalyst provided by aluminum chloride or aluminum bromide, or a mixture of these two compounds. The rate of isomerization is increased by having the reaction run in the presence of an aroyl halide, such as benzoyl chloride or isophthaloyl chloride.

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