Method for producing fully oxidized white liquor

Paper making and fiber liberation – Processes of chemical liberation – recovery or purification... – With regeneration – reclamation – reuse – recycling or...

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162 29, 423551, D21C 1104

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active

055000851

ABSTRACT:
A method for white liquor oxidation in a kraft mill utilizes a two-stage selective oxidation system in which the first stage is operated to remove sulfide while the second stage is operated to oxidize a significant fraction of the remaining oxidizable sulfur compounds to sulfate. The resulting selectively oxidized white liquor products are used as alkali sources for various process steps in the mill. Optionally, white liquor can be oxidized in a single stage to convert a significant fraction of the oxidizable sulfur compounds to sulfate. Methods for controlling the selective oxidation process are disclosed.

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Baczynska, K. "Use of White/Green Liquors as Alkalis in the Oxygen . . . Pulp"-Przeglad Papier 35 Jun. 1979, #6:193-195.
O'Hern, H. A.-"Product Distribution & Reaction Rates in Green Liquor Oxidation", Oct. 1972 pp. 139-151.
McDonald, Ronald "The Pulping of Wood." vol. 1, 1969, McGraw Hill Book Company, pp. 600-601.
Novikova, A. I. et al. "Oxidation of White Liqour by Oxygen." Khim. Tekhnol. Tsellyul. Ee Prorzvodnykh 1985, pp. 49-52.
Ulmgren, Per et al. "The Manufacture of Sulfur-Free Alkali in Kdraft Pulp Mill." Nordic Pulp and Paper Res. Journal No. 4 1988: pp. 191-197.

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