Method for producing aryl alkyl hydroperoxides

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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5689098, 568911, 546255, 544180, 544242, 544336, C07C 2950, C07C 2716, C07C 2710

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059455721

ABSTRACT:
A method for producing aryl alkyl hydroperoxides which comprises selectively oxidizing an aryl alkyl hydrocarbon having the formula: ##STR1## wherein P and Q are hydrogen or an alkyl and may be the same or different from each other; x is an integer of 1-3; and Ar is an aromatic hydrocarbon group having a valence of x, with an oxygen-containing gas in the presence of a transition metal complex which contains, as a ligand, a cyclic polyfunctional amine compound having at least three nitrogen atoms in the ring forming molecular chain or an open chain polyfunctional amine compound having at least three nitrogen atoms in the main chain of the molecule.

REFERENCES:
patent: 4459427 (1984-07-01), Middleton et al.
patent: 5847227 (1998-12-01), Fujita et al.
Chemicals Abstracts, vol. 78, No. 21, Abstracts No. 135806, XP002032832, Columbus, Ohio, US; May 28, 1993.
Database WPI Week 7534, AN 75-56360, XP002032834, Derwent Publications Ltd., London, GB, Apr. 8, 1975.
Chemical Abstracts, vol. 79, No. 9, Abstract No. 52880, XP002032833, Columbus, Ohio, US; Sep. 3, 1973.
Chemistry Letters, vol. 2, pp. 103-106, Hara et al.: "Oxidation of Cumene", 1973.

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