Method for preparation of carboxylic acids

Organic compounds -- part of the class 532-570 series – Organic compounds – Fatty compounds having an acid moiety which contains the...

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554132, 554134, C07C 5116

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active

059395729

ABSTRACT:
A method for preparing a carboxylic acid is provided. The method includes contacting an olefinic compound or a vicinal dihydroxy compound with oxygen in the presence of a protic organic solvent, an inorganic oxide catalyst and a peroxidant such as hydrogen peroxide or an peralkanoic acid. The inorganic oxide catalyst includes an oxide of tungsten, molybdenum, niobium, vanadium, tantalum, titanium, or yttrium.

REFERENCES:
patent: 2744928 (1956-05-01), Smith et al.
patent: 3855257 (1974-12-01), Pultinas, Jr.
patent: 3895040 (1975-07-01), Miyazaki et al.
patent: 4532079 (1985-07-01), Venturello et al.
Venturello, C. et al., "Oxidative Cleavage of 1,2-Diols to Carboxylic Acids by Hydrogen Peroxide," J. Org. Chem., 51(9):1599-1602 (1968).

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