Method for nucleation of CVD tungsten films

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

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438674, 438677, 427253, 427255, 4272551, 4272557, C23C 1608

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active

057958246

ABSTRACT:
A tungsten (W) film is formed on a surface of a semiconductor substrate by providing to that surface gas mixtures tailored for both reduced gas phase nucleation of particulates (GPN) and attack of exposed silicon (Si) or titanium (Ti) surfaces (Device Attack) while maintaining a high W deposition rate. An initiation step is performed where the surface is preconditioned with hydrogen (H.sub.2) and silane (SiH.sub.4). A subsequent nucleation step then uses a mixture of H.sub.2 and SiH.sub.4 to reduce tungsten hexafluoride (WF.sub.6) and thus form a first thickness of the W film. In some embodiments, an alternate gas mixture can be employed to form a second thickness of W on the surface of the semiconductor substrate.

REFERENCES:
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patent: 5342652 (1994-08-01), Foster et al.
patent: 5472508 (1995-12-01), Sexena
F. Cumplan et al., "Parametric Study of H.sub.2 Doped SiH.sub.4 /Wf.sub.6 Nucleation on Ti/TiN by Tungsten CVD Process," Advanced Metallization and Interconnect Systems for ULSI Application in Oct. 1995, pp. 529-534

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