Method for modifying surface of counter electrode and...

Batteries: thermoelectric and photoelectric – Photoelectric – Cells

Reexamination Certificate

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C136S252000, C136S264000, C438S057000, C438S098000

Reexamination Certificate

active

07947896

ABSTRACT:
Disclosed herein is a method for modifying the surface of a counter electrode. According to the method, the surface modification is achieved by treating the surface of a counter electrode with a polyethylene glycol derivative having a pendant group at one end. Also disclosed is a counter electrode whose surface is modified by the method. The electron transfer rate at the interface between the counter electrode and an electrolyte layer of a photovoltaic device is increased and the affinity of the counter electrode for the electrolyte layer is improved, resulting in an improvement in the power conversion efficiency of the photovoltaic device.

REFERENCES:
patent: 2004/0163700 (2004-08-01), Mizuta et al.
patent: 2005/0285101 (2005-12-01), Hanson et al.
patent: 2007/0119048 (2007-05-01), Li et al.
Zhang et al., Voltametric Behavior of Noradrenaline at 2-Mercaptoethanol Self-Assembled Monolayer Modified Gold Electrode and its Analytical Application, Chemistry and Material Science, Hubei University, Sensors, vol. 3, pp. 61-68, 2003.
Wang et al. (A Novel High-Performance Counter Electrode for Dye-Sensitized Solar Cells, Institute of Chemistry, Chinese Academy of Scineces, Electrochimica Acta, vol. 50, pp. 5546-5552, 2005.
Nogueira, et al; “Bye-Sensitized Nanocrystalline Solar Cells Employing a Polymer Electrolyte”; Adv. Mater.; 13; pp. 826-830; Jun. 5, 2001.

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