Semiconductor device manufacturing: process – Chemical etching – Vapor phase etching
Reexamination Certificate
2000-12-22
2002-11-12
Utech, Benjamin L. (Department: 1765)
Semiconductor device manufacturing: process
Chemical etching
Vapor phase etching
C438S712000, C438S717000, C438S723000, C438S725000
Reexamination Certificate
active
06479391
ABSTRACT:
FIELD OF THE INVENTION
The present invention relates to a method for making semiconductor devices that include dual damascene interconnects.
BACKGROUND OF THE INVENTION
Dual damascene metal interconnects may enable reliable low cost production of integrated circuits using sub 0.25 micron process technology. The lithographic process used to define dual damascene features can be relatively complex. Unlike conventional processes, which only require etching vias through a dielectric layer, processes for making dual damascene structures also require etching trenches into that layer.
One way to form such a device begins by forming a dual hard mask on top of a dielectric layer prior to patterning the trench and via, as illustrated in
FIG. 1
a.
That figure represents a structure that includes a substrate
10
upon which is formed conductive layer
11
, barrier layer
12
, dielectric layer
13
(e.g., a polymer based film), silicon dioxide hard mask
14
and silicon nitride hard mask
15
. In this process for making a dual damascene structure, a trench is then patterned using conventional lithography steps. Etching the portion of silicon nitride hard mask
15
that the photoresist layer did not protect produces the structure illustrated in
FIG. 1
b.
Silicon dioxide hard mask
14
serves as an etch stop for that process step.
Photoresist layer
16
is then deposited and patterned to define a via, as shown in
FIG. 1
c.
Exposed portions of hard masks
14
and
15
are removed, generating the structure shown in
FIG. 1
d,
followed by etching via
17
partially through dielectric layer
13
to produce the structure shown in
FIG. 1
e.
The portion of silicon dioxide hard mask
14
that is not protected by silicon nitride hard mask
15
is then removed, producing the
FIG. 1
f
structure. Dielectric layer
13
is then further etched to produce the structure shown in
FIG. 1
g.
The exposed portion of barrier layer
12
is then removed, as illustrated in
FIG. 1
h,
to complete via
17
and trench
18
. That via and trench may then be filled with a conductive material, e.g, copper, using techniques that are well known to those skilled in the art.
As is apparent from
FIGS. 1
a
-
1
h,
this process leaves little room for error when lining up the mask that will define the via. The alignment budget for that mask is, in essence, dictated by the trench's width. Unless part of the mask lines up with part of the trench, separation will result between the subsequently formed via and trench, which will yield an inoperable device. Other problems may arise when a polymer based film is used to make the dielectric layer. Because such a film may have relatively poor mechanical properties, structural instability may result. In addition, using such a film may cause via profile degradation. Using a carbon doped oxide instead may enhance the resulting film's mechanical properties, but may lead to increased etch bias.
Accordingly, there is a need for a process for making a dual damascene interconnect using a multilayer hard mask that will increase the alignment budget for via and trench formation. In addition, there is a need for a process that enhances the mechanical integrity, and the via profile and etch bias, of the resulting interconnect. The method of the present invention provides such a process.
REFERENCES:
patent: 6066569 (2000-05-01), Tobben
patent: 6156643 (2000-12-01), Chan et al.
patent: 6184142 (2001-02-01), Chung et al.
patent: 6291887 (2001-09-01), Wang et al.
patent: 6309962 (2001-10-01), Chen et al.
patent: 6312874 (2001-11-01), Chan et al.
Jan Chia-Hong
Leu Jihperng
Morrow Patrick
Deo Duy-Vu
Intel Corporation
Seeley Mark V.
Utech Benjamin L.
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