Method for fractionation of lignins from steam exploded lignocel

Paper making and fiber liberation – Processes of chemical liberation – recovery or purification... – Including recovery of organic by-product

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162 16, 162 21, 162 60, 162 72, 162 77, 162 88, 162 89, 530500, 530507, D21B 136, D21C 318, D21C 320, D21C 326

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049666509

ABSTRACT:
The chemical components of lignocellulosic material which have been dissociated by a steam explosion process can be extracted from the mixture of components using a solvent extraction process. The solvents are water, alcohol and a mild caustic in that order, or the alcohol step can be by-passed and only water and caustic are used. The caustic is a stronger solvent and it will extract the alcohol solubles along with the caustic only solubles. The eluant from the these extractions contains a range of lignin derived substances, which have different applications, such as thermoplastic and thermosetting characteristics. This invention describes a method for partitioning these lignin components into reproducible fractions having definable characteristics for particular applications. For instance, many copolymer applications require a thermosetting only fraction of the lignin. Other applications require a thermoplastic only lignin. The patent also describes a process for converting the thermoplastic lignin fraction to thermosetting lignin.

REFERENCES:
patent: 2752394 (1956-06-01), Sorensen
patent: 4453004 (1984-06-01), Nelson
patent: 4470851 (1984-09-01), Pazner et al.

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