Method for forming ultra-shallow junctions using laser...

Semiconductor device manufacturing: process – Introduction of conductivity modifying dopant into... – By application of corpuscular or electromagnetic radiation

Reexamination Certificate

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C438S550000

Reexamination Certificate

active

06475888

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates generally to a method for fabricating semiconductor devices and, more particularly, to a method for forming ultra-shallow junctions using laser annealing with an amorphous carbon layer as an energy absorber layer.
2. Description of the Background Art
As a design rule for high performance semiconductor device is reduced, recent research and development efforts are focused on formation of ultra-shallow junction. Therefore, research and development are being in progress.
For example, in semiconductor devices having a gate length of less than 250 nm, that is, in MIS (Metal-Insulator-Semiconductor) transistors, source/drain extension (hereinafter, referred to as SDE) doping layers having ultra-shallow junctions are formed on inner sides of source/drain regions. In a conventional method, this SDE layer is formed by implanting impurity ions and performing a rapid thermal process (hereinafter referred to as RTP) and thereby, activating dopants in the SDE doping layer and source/drain regions
The above-described method is advantageous in forming a transistor having gate lengths of more than 130 nm. However, it has several drawbacks when applied to high performance transistors having gate lengths of less than 100 nm.
First, when the high performance transistor is formed, it is required to maintain a junction depth of the SDE doping layer less than 35 nm. However, when junction depth of the SDE doping layer is less than 35 nm, a desired doping degree of the SDE doping layer is not maintained due to the solid solubility limit, thereby causing abrupt increase of sheet resistance. As a result, it is difficult to obtain a high performance transistor.
Therefore, laser thermal processes have been developed to solve the above problems.
FIG. 1
is a graph plotting sheet resistance versus junction depth in each method for forming ultra-shallow junctions, where reference code A indicates sheet resistance according to junction depths in which RTP is performed to activate doped impurities and reference code B indicates those in which laser annealing is performed. Reference code C indicates scaling rule requirements of junction depth and sheet resistance.
As shown in
FIG. 1
, when RTP is performed to activate impurities (A), scaling rule requirements of junction depth and sheet resistance are not fulfilled. However, when laser annealing is performed (B), they are fulfilled.
A fabrication method for making 70 nm MOSFET using laser annealing, as proposed by Bin Yu et al., will be described with reference to
FIGS. 2A
to
2
C. (IEDM 1999, “70 nm MOSFET with Ultra-Shallow, Abrupt, and Super-Doped S/D Extension Implemented by Laser Thermal Process”).
Referring to
FIG. 2A
, a gate
23
having a gate oxide film
22
is formed on an active region of silicon substrate
20
defined by a trench type isolation layer
21
through well-known processes. Then, a first spacer
24
, made of silicon nitride layer (Si
3
N
4
), is formed on the sidewalls of the gate
23
. An ion implantation process and a rapid thermal process are sequentially performed to form source/drain regions
25
a
and
25
b
on the silicon substrate
20
at both sides of gate
23
, including the first spacer
24
.
Referring to
FIG. 2B
, the first spacer
24
is removed and ions are implanted on the resulting structure to form a SDE doping layer. Then, laser annealing is performed to selectively melt and solidify the amorphous surfaces of source/drain regions
25
a
and
25
b
, thereby forming a SDE doping layer
26
, activated in high concentration on silicon substrate
20
at both sides of gate
23
.
Referring to
FIG. 2C
, a second spacer
27
is formed on sidewalls of gate
23
by oxide film deposition and blanket etching and then a metal layer, for example, a cobalt layer is deposited to a predetermined thickness on the resulting structure. Then, annealing is performed so that cobalt of the cobalt layer may respond to substrate silicon, thereby forming a cobalt silicide layer
28
on the surface of source/drain regions
25
a
and
25
b
and on the upper surface of the gate
23
.
Ken-ichi Goto proposed a method that the activated dopant concentration of a contact formation region can be maintained at greater than 10
21
/cm
3
by using laser annealing after implanting the source/drain ions to improve contact resistance. The ultra-low resistance contact formation method by laser annealing will be described with reference to
FIGS. 3A
to
3
C. (IEDM 1999, “Ultra-Low Contact Resistance for Deca-nm MOSFETs by Laser Annealing”).
Referring to
FIG. 3A
, a gate
33
having a gate oxide film
32
is formed on an active region of silicon substrate
30
defined by isolation layer
31
. And, ions are implanted to form source/drain extension doping layer and rapid thermal treatment is performed thereby, forming a SDE doping layer
34
electrically activated on the surface of substrate
30
at both sides of the gate
33
.
Referring to
FIG. 3B
, a spacer
35
is formed on sidewalls of gate
33
and ions are implanted, thereby forming inactivated doping layer
36
to form source/drain regions on a silicon substrate
30
at both sides of gate including the spacer
35
.
Referring to
FIG. 3C
, in order to obtain ultra-low resistance contact, source/drain regions
36
a
and
36
b
are formed using laser annealing and, at the same time, the surface of the source/drain regions
36
a
and
36
b
and the upper surface of gate
33
are transformed into an activated doping layer
37
in a high concentration.
Thereafter, a rapid thermal treatment at a low temperature of 800° C. and interconnection process are performed to complete the formation of the transistor.
The above-mentioned method using laser annealing is advantageous to fabrication of a transistor having a silicon gate. However, as shown in
FIG. 4
, it is difficult to apply to fabrication of a transistor having a metal gate
42
d
on the upper part of a gate
42
, since the metal gate
42
d
is transformed during laser annealing due to the fact that the metal gate
42
d
has high laser absorption rate. In
FIG. 4
, reference numeral
40
indicates a silicon substrate, reference numeral
41
is a isolation layer, reference numeral
42
a
is a gate insulating layer, reference numeral
42
b
is a silicon gate, reference numeral
42
c
is a diffusion preventing layer, reference numeral
43
a
is a source region, reference numeral
43
b
is a drain region and reference numeral
44
is a SDE doping layer.
In order to solve the above-described problems, a method has been developed that includes a step prior to laser annealing, in that a metal laser absorber layer, for example, a refractory metal thin film such as a Ti/TiN layer, is deposited on the surface of the substrate, thereby preventing an excessive rise in temperature of the metal gate. However, problems exist in that the melting point of Ti is 1,667° C., very similar to that of Si, 1,412° C. Therefore, the Ti components remain in the oxide film after the Ti/TiN layer is removed.
SUMMARY OF THE INVENTION
Therefore, an object of the present invention is to provide a method for forming an ultra-shallow junction capable of preventing transformation of a metal gate using laser annealing.
Another object of the present invention is to provide a method for forming an ultra-shallow junction using laser annealing to be applied to fabrication of a high performance device without transformation of the gate.
In order to achieve the above-described objects, an embodiment of the present invention comprises the steps of: preparing a silicon substrate having isolation layers thereon; forming a gate which has a stacked structure of a gate insulating layer, a polysilicon layer and a metal layer on the silicon substrate; forming a sacrificial spacer on sidewalls of the gate; forming source/drain regions on the silicon substrate region at both sides of the gate including over the sacrificial spacer; removing the sacrificial spacer; doping impurities to form a source/drain extension doping

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