Method for forming inter-metal dielectrics

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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C438S597000, C438S598000, C438S618000, C438S622000, C438S624000, C438S625000, C438S626000, C438S787000, C438S788000, C438S792000

Reexamination Certificate

active

06265298

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a semiconductor process. More particularly, the present invention relates to a method for forming inter-metal dielectrics (IMD) on a semiconductor substrate.
2. Description of Related Art
With the increased integration in integrated circuits (IC), a conventional wafer can no longer provide sufficient area for interconnects. In order to satisfy performance requirements, design rules of forming more than two metal layers for interconnects are gradually applied in integrated circuits. An inter-metal dielectric (IMD) layer is formed between two metal layers for isolation. Since a metal layer and a dielectric layer are alternately laminated to form metal interconnects, the planarization of the dielectric layer is more important. If the result of the planarization is not ideal, the uneven surface of the dielectric layer causes misalignment while a subsequent photolithography process is performed so that the pattern cannot accurately transfer onto the metal line and the process becomes more difficult.
In general, a spin-on glass (SOG) method is used in metal interconnects fabrication. The method includes coating SOG material on a wafer. Then a curing treatment is performed, in which the unwanted solvent of the SOG material is removed at a high temperature by a thermal treatment to cure the SOG material. Thus, a SOG layer is formed. The SOG material has better step coverage ability and better gap filling ability, therefore, the voids between the metal layers can be easily filled. In SOG application, a sandwich-type structure is provided, in which a dielectric layer made of SOG material is formed between two silicon oxide layers formed by chemical vapor deposition (CVD). Thus, the properties of the SOG layer such as dielectric constant cannot be affected in a subsequent process.
FIGS. 1A through 1B
are schematic, cross-sectional views showing a conventional method of forming an inter-metal dielectric layer.
As shown in
FIG. 1A
, a semiconductor substrate
11
is provided. A metal line
10
is formed over the substrate
11
. A silicon oxide layer
12
, a SOG layer
14
, and a silicon oxide layer
16
are subsequently formed on the metal line
10
to form a sandwich type structure.
Turning to
FIG. 1B
, a chemical-mechanical polishing (CMP) process is performed to planarize the silicon oxide layer
16
. A cap oxide layer
18
is formed on the silicon oxide layer
16
to cover some scratches generated while performing the CMP process. Thus, an inter-metal dielectric layer
19
with a flat surface is formed.
However, while performing the CMP process, no layers, including the SOG layer
14
and the silicon oxide layer
16
, are hard enough to serve as a stop layer, therefore the metal line
10
is usually polished and damaged.
One conventional method for solving the above-mentioned problem is to implant ions into the SOG layer after the SOG layer is cured. This implantation makes the cured SOG layer harder, so it can be used as a stop layer. However, in this method, two steps including a curing treatment and an ion implantation are needed so that the process is more complicated, the device throughout is thus decreased and the cost is increased.
Another conventional method is to cure the SOG layer with a high-energy, high-dosage electron beam, so that the metal line is not damaged while performing the CMP process and the metal line is not affected while subsequently forming a via hole. However, although no additional step is added in this method, the dielectric constant of the SOG layer between the two metal layers is increased so as to decrease the isolation effect of the metal line and then, to affect the RC delay time. Moreover, SOG shrinkage adversely affect the planarization of the SOG layer.
Therefore, it is desirable to provide a method which can resolve the above-mentioned problems.
SUMMARY OF THE INVENTION
Accordingly, the present invention provides a method for forming inter-metal dielectrics (IMD) on a semiconductor substrate, which does not adversely affect the dielectric constant of an inter-metal dielectric layer and does not damage to a conductive line during a chemical-mechanical polishing (CMP) process.
To achieve these and other advantages and in accordance with the purpose of the invention, as embodied and broadly described herein, the invention provides a method for forming inter-metal dielectrics (IMD) over a semiconductor substrate, wherein a conductive line is formed thereon. A first dielectric layer is formed over the conductive line. A second dielectric layer is formed on the first dielectric layer by a spin-on glass method. A curing treatment with an electron beam having a low energy and a high dosage is performed to cure an upper portion of the second dielectric layer so that a cured third dielectric layer is formed on the second dielectric layer. A fourth dielectric layer is formed on the cured third dielectric layer. A chemical-mechanical polishing process is performed using the cured dielectric layer as a stop layer. A cap layer is formed on the fourth dielectric layer.
The present invention uses an electron beam with a low energy and a high dosage, so that only a portion of the SOG layer is cured. Therefore, the dielectric constant of the SOG layer in the present invention is lower than that in the conventional method. Furthermore, the shrinkage of the SOG layer formed in accordance with the present invention is reduced and the crack thereof.
It is to be understood that both the foregoing general description and the following detailed description are exemplary, and are intended to provide further explanation of the invention as claimed.


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