Method for fabricating contact of semiconductor device

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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Details

C438S597000, C438S612000, C438S613000

Reexamination Certificate

active

06337273

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a semiconductor device, and more particularly, to a method for fabricating a contact of a semiconductor device which efficiently removes an etching damage layer and a residual layer when fabricating a contact of a semiconductor memory device, thereby improving a motion characteristic of the device.
2. Background of the Related Art
Generally, in a device above 64M DRAM, a Self Aligned Contact(SAC) process is used when fabricating a contact which connects a capacitor and a cell transistor.
The Self Aligned Contact is formed by a dry etching process using a plasma. The plasma consists of free electrons generated by an RF discharge at a low pressure of 0.01~10 torr and etching gas ions, and is chemically very active to react with atoms of surrounding layers. If the plasma becomes volatile when reacted with the atoms of the surrounding layers, a compound of the plasma and the atoms is evaporated from the surface of a semiconductor substrate.
Meanwhile, when manufacturing a semiconductor device, a photoresist, a polysilicon layer, a metal layer or their layered film are also dry etched, and particularly, the metal layer is etched using a Cl
2
, and the polysilicon layer using SF
6
. A silicon oxide film (SiO
2
) is etched using CF
4
, and the photoresist using O
2
.
In this instance, since the SiO
2
is used as an insulating layer between the capacitor and the cell transistor, the CF
4
is used for etching the insulating layer. On the other hand, C
4
F
8
is usually used in the SAC process.
The related art method for fabricating a contact of a semiconductor device will be described below with reference to the attached drawings.
FIGS. 1
a
to
1
g
illustrate sections showing the related art Process steps for fabricating a contact of a semiconductor device, and
FIG. 2
illustrates a section showing a lower structure of a contact hole after performing a light etching for completely removing a plasma damage region.
First, as shown in
FIG. 1
a
, a gate oxide film
3
is formed on a semiconductor
1
, at which an active region and a device isolation region are defined by a field oxide film
2
.
Subsequently, as shown in
FIG. 1
b
, a doped polysilicon
4
, a tungsten silicide (WSi)
5
, and a nitride film (Si
3
N
4
)
6
are sequentially deposited on the gate oxide film
4
.
Then, as shown in
FIG. 1
c
, a photoresist (not shown) is applied on the nitride film
6
, and is patterned by exposing and developing process. The oxide film
6
, the tungsten silicide
5
, the doped polysilicon
4
, and the gate oxide film
3
are then selectively etched using the patterned photoresist film as a mask, to form gate and cap insulating layers
4
a
,
5
a
and
6
a.
Thereafter, a low concentration impurity ion is implanted using the gate and cap insulating layers
4
a
,
5
a
and
6
a
as masks, to form a low concentration impurity region
7
within a surface of the semiconductor substrate
1
at both sides of the gate, in order to be used as a Lightly Doped Drain (LDD).
Subsequently, as shown in
FIG. 1
d
, a nitride film Si
3
N
4
is deposited on an entire surface of the semiconductor substrate
1
which is exposed, including the gate and cap insulting layers
4
a
,
5
a
and
6
a
. The nitride film is then etched back, to form a gate sidewall
8
at sides of the gate and cap insulating layers
4
a
,
5
a
and
6
a
. Then, a high concentration impurity ion is implanted using the gate and cap insulating layers
4
a
,
5
a
and
6
a
, including the sidewall
8
, as a mask, to form a source/drain region
9
of an LDD structure.
As shown in
FIG. 1
e
, an insulating layer
10
is formed on an entire surface of the semiconductor substrate
1
including the gate and cap insulating layers
4
a
,
5
a
and
6
a
. Then, a photoresist
11
is applied thereon and is selectively patterned, to form a storage node contact mask.
As shown in
FIG. 1
f
, the exposed insulating layer
10
is selectively etched by the SAC process using a plasma etching device, using the selectively patterned photoresist
11
as a mask, to form a contact hole
12
. At this instance, a large quantity of carbon (C) ions are generated during the etching process, because the C
4
F
8
is implanted within the etching device to induce the plasma. The C
4
F
8
is used to improve an efficiency of the SAC process.
An SiC layer
13
is formed on a surface of the semiconductor substrate
1
by the carbon ions, at which a contact hole
12
is formed. Referring to an enlarged view of
FIG. 1
f
, it is understood that a plasma damage layer
14
and the SiC layer
13
are formed at a bottom surface of the contact hole
12
(a surface of the semiconductor substrate), during the etching of plasma.
The SiC layer
13
is formed of a carbon component of the C
4
F
8
and Si of the semiconductor substrate
1
, and the plasma damage layer is a part in which Si gratings are damaged by a physical damage of the plasma.
The SiC layer
13
and the plasma damage layer
14
increase a contact resistance between a capacitor and a cell transistor which will be formed at a later process, as well as generating a leakage current.
Accordingly, as shown in
FIG. 1
g
, a light etching process for removing the SiC layer
13
and the plasma damage layer
14
is performed after removing the photoresist
11
, using an additional etching device having anisotropic low etching ratio.
During this light etching process, a substantial amount of O
2
is used for preventing a re-formation of the SiC layer.
However, even if the process for removing the Sic layer
13
and the plasma damage layer
14
is performed using the light etch process, a residual SiC layer+plasma damage layer
15
is remained on a surface of the semiconductor substrate, as shown in an enlarged view of
FIG. 1
g.
If, as shown in
FIG. 2
, a time of the light etching process is increased for removing the residual SiC+plasma damage layer
15
, an isotropic etching ratio is increased accordingly even if the etching device having isotropic low etching ratio is used for the light etching process.
That is, inner parts of the source/drain region
9
with the LDD structure are dented, as in the part A shown in FIG.
2
.
It is apparent that, by performing the light etching process in the SAC process, a restoration ratio of life time is improved.
FIG. 3
illustrates a change in the life time when using a TCA
3822
light etching device. As shown in the drawing, a time from excitation of electrons to extinction thereof is increased, if the light etching is performed with sufficient time.
FIG. 3
illustrates a result of the light etching using only a source power, under a condition of 600 mTorr, 100 W, 45 O
2
and 35 CF
4
.
However, the related art method for fabricating a contact of a semiconductor device has the following problems.
First, since an additional etching device having anisotropic low etching ratio is used for a long time instead of using an etching device used in the SAC process, a Turn Around Time (TAT) is increased and maintaining the device becomes difficult.
Second, in case of a general light etching process for removing the SiC layer and the plasma damage layer formed during the SAC process, a contact resistance is increased, as well as a leakage of current stored in the capacitor, because of the residual SiC layer+plasma damage layer.
As a result, a motion characteristic of a device is deteriorated. Particularly, in case of a memory device such as a DRAM, a reliability of the device is deteriorated because of inequality in refreshing movements, or reduction of refreshing time.
Finally, when the time of light etching is increased for removing the residual SiC layer and the plasma damage layer, the process becomes an isotropic etching. Accordingly, an inner part of the source/drain region with an LDD structure is damaged, thereby causing an inequality in the motion characteristic of the device, as well as deteriorating an yield.
SUMMARY OF THE INVENTION
Accordingly, the present invention is directed to

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