Method for dehydrochlorinating 1,1,1,-trichloro-2,2-bis(4-hydrox

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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528202, 528219, C07C 3700

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active

041170180

ABSTRACT:
A method is described for dehydrochlorinating 1,1,1-trichloro-2,2-bis(4-hydroxyphenyl)ethane employing a refluxing dipolar aprotic solvent, such as dimethylformamide, containing a lithium halide catalyst to produce a crystalline product consisting essentially of 1,1-dichloro-2,2-bis(4-hydroxyphenyl) ethylene. The crystalline product can be isolated in substantially pure form and converted to a high impact, flame retardant polycarbonate.

REFERENCES:
McCelland et al., J.C.S. Perkin II, pp. 1818-1822, 308 (1972).
Holysz, J.C.S., 75, pp. 4432-4437 (1953).
Porejko et al., Polimery, 13, (2), 55 (1968).
Sobicaewski et al., "On the Stability of Polycarbonates from Chlorobisphenols," Inst. for Plastics, Warsaw, 10/26/1967.
Dubkowski et al., "Synthesis of Polycarbonates by Interfacial Method,".
Ibid, 428-431 (1970).
Wielgosz et al., Polimery-Tworzywa Wielkoczasteczkowe, (1971), pp. 495-500.
Wielgosz et al., Polimery, 17, 76 (1972).
Trojna et al., Chem. Listy, 51, 752-755 (1957).
Hubacher, J. Org. Chem., 24, 1949-1951, (1959).
Grummit et al., Org. Synth., 26, 21 (1946).

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