Paper making and fiber liberation – Processes of chemical liberation – recovery or purification... – Waste paper or textile waste
Reexamination Certificate
1998-12-15
2001-03-06
Nguyen, Dean T. (Department: 1731)
Paper making and fiber liberation
Processes of chemical liberation, recovery or purification...
Waste paper or textile waste
C209S164000, C209S170000, C210S195100, C210S221200
Reexamination Certificate
active
06197153
ABSTRACT:
BACKGROUND AND SUMMARY OF THE INVENTION
The object of the invention is to provide a method for de-inking paper pulp from old papers.
The used paper recycling process starts with the separation, by stirring in water, of the bales of old papers in order to obtain a pulp. This pulp is then screened in order to remove foreign bodies, known as contaminating substances, such as staples, paper clips, and plastic elements.
This pulp thus rid of coarse foreign bodies then comprises three types of components:
fibers: i.e. the non-mineral part retained on a 100-mesh sieve;
fines: i.e. the complement of fibers in the non-mineral part;
fillers: i.e. the mineral part remaining after the pulp has been put through an oven at 470°.
The fillers come, on the one hand, from the usually white-colored, relatively large mineral particles added to paper during production thereof to endow it with opacity and whiteness, and, on the other hand, from the coating of coated paper. In addition to mineral particles, the coating contains binders which are products similar to glue, and numerous other components only present in a very small proportion. Of the fillers used, mention might be made of e.g. carbonate (chalk); by binders is meant products similar to glues.
In order to develop certain physical features of the paper produced, the fibers have to be refined. This operation also generates fine elements which are fiber fragments and which are not retained by the 100-mesh grid.
The fines are therefore comprised of fragments of fiber, of the non-mineral fraction of the coating of coated paper, of the organic part of ink and, finally, of the organic part of the small contaminating substances that pass through the 100-mesh sieve.
Of course, bales of recycled old papers contain all possible kinds of paper, ranging from cardboard to onion skin paper, these papers being coated or otherwise, and comprising all sorts of contaminating substances.
Printing inks must be added to the foresaid.
The next stage in the processing is de-inking which is usually performed by injecting air into the pulp in order to create air bubbles to the walls to which ink particles become attached. This aeration operation causes the appearance, on the surface of the mass of pulp, of a foam comprised of bubbles which walls retain particles of ink, and this foam is then evacuated.
French Patent Application No. 94-02886 dated Mar. 11, 1993 describes a method of de-inking by means of air bubbles, consisting in creating, in an enclosures, by successive recycling phases of the pulp, stage by stage, from the top towards the bottom of the enclosure, a downward movement of the pump mass by stages, this movement being crossed by an upward movement of bubbles so that each level stage (or each level of recycling), the pulp current is passed through by a stream of bubbles practically perpendicular to the pulp current.
In reference to
FIG. 1
, it can be seen that the device is comprised of an enclosure
1
, arranged vertically and comprising, from the top downwards, four inlet openings E bearing the references E
1
, E
2
, E
3
, E
4
and four outlet opening referenced S
1
, S
2
, S
3
, and S
4
, these opening being located at the base of four deflectors D
1
, D
2
, D
3
and D
4
composed of a vertical part and a slanted part.
The inlet opening E
1
, which is at the highest level, is the one through which the pulp to be de-inked will arrive.
To each inlet opening such as e.g. E
1
corresponds an outlet opening S
1
so that the major part of the (or even the entire) flux entering the enclosure at E
1
will exit at S
1
. The outlet S
1
is connected to the inlet E
2
, which is situated below the level of the inlet E
1
so that the product thus recycled will be recycled at a lower level.
In the example represented, the outlets S
1
, S
2
, S
3
, and S
4
are situated at a level below that of the inlets E
1
, E
2
, E
3
, E
4
to which they correspond, though this is not obligatory.
In this example, the second inlet E
2
is located slightly below the first outlet S
1
; the third inlet E
3
is located slightly below the second outlet S
2
; the fourth inlet E
4
is located slightly below the third outlet S
3
; the fourth outlet S
4
is situated in the bottom part of the enclosure
1
.
The outlet S
4
is the one via which the pulp, rid of its ink, is evacuated.
In its upper part, the enclosure
1
comprises one or more openings M for foam evacuation purposes.
The outlet S
1
is connected to the inlet E
2
by means of a pipe
2
upon which a pump P
1
is arranged. Similarly, the outlet S
2
is connected to the inlet E
3
with a pump P
2
placed in between, and openings S
3
and E
4
are connected via a pump P
3
.
The pulp is fed(by any appropriate means), via E
1
into the enclosure
1
which is filled up to the level N situated above the inlet E
1
and below the foam evacuation pipe M.
Once this level has been reached, the recycling pumps P
1
, P
2
and P
3
are activated.
The pulp arriving via E
1
is entirely or partly evacuated via the outlet S
1
, and the pipe
2
enables the pulp to be reintroduced into the enclosure via the inlet E
2
.
The pulp reintroduced via E
2
is entirely or partly evacuated via the outlet S
2
and then reintroduced via E
3
; after E
3
, it exits via S
3
before being reintroduced via E
4
; from E
4
it then moves towards outlet S
4
from which is evacuated by the pipe
7
.
Preferably, the pump P
3
, which is the pump by which the pulp is recycled to the lowest part of the enclosure, is associated with an air injector I
3
supplied by an air duct
6
. As a result, the flow of pulp arriving at E
4
, which is the lowest inlet openings of the enclosure, is full of air bubbles. These air bubbles will rise so that the pulp recycled at S
3
, S
2
and S
1
is again mixed with the bubbles and therefore that the bubbles which finish by arriving at the level M have been mixed into the pulp, and been stirred around in the pulp several time over and so that the probability of collision between the bubbles and the ink particles will have been increased.
Additional air injectors I
2
and I
1
can be arranged in association with the pumps P
2
and P
1
, thereby increasing the quantity of bubbles rising up through the descending mass of pulp.
In the example represented, there are three recycling circuits S
1
-E
2
, S
2
-E
3
, S
3
-E
4
; however, the invention is obviously not limited to this particular case.
This method enables a very pure and almost completely de-inked pulp to be obtained.
However, it has been observed that the foam contains a lot of fillers, fines and fibers of small dimensions, either because these particles were mechanically conveyed by the bubbles or because they were bonded by the ink to the bubbles.
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patent: 3865719 (1975-02-01), Holik et al.
patent: 4094783 (1978-06-01), Jackson
patent: 4186094 (1980-01-01), Hellberg
patent: 4288319 (1981-09-01), Heijs et al.
patent: 4331534 (1982-05-01), Barnscheidt
patent: 4347128 (1982-08-01), Barnscheidt
patent: 4399028 (1983-08-01), Kile et al.
patent: 4721562 (1988-01-01), Barnscheidt et al.
patent: 4722784 (1988-02-01), Barnscheidt
patent: 4952308 (1990-08-01), Chamberlin et al.
patent: 5028315 (1991-07-01), Cruea et al.
patent: 5234112 (1993-08-01), Valenzuela et al.
patent: 5242585 (1993-09-01), Krofta
patent: 5454935 (1995-10-01), Magaraggia
patent: 5650044 (1997-07-01), Serres
patent: 35 24 071 (1987-01-01), None
patent: 42 04 915 (1993-08-01), None
patent: 0 122 747 (1984-10-01), None
patent: 0 198 737 (1986-10-01), None
patent: 0 305 251 (1989-03-01), None
patent: 0 798 416 (1997-10-01), None
patent: 2 347 984 (1977-11-01), None
patent: 2 717 192 (1995-09-01), None
patent: WO 80/00423 (1980-03-01), None
patent: WO 93/04784 (1993-08-01), None
E & M Lamort
Nguyen Dean T.
Nixon & Vanderhye P.C.
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