Method and system for improving the manufacturing of metal...

Semiconductor device manufacturing: process – Coating with electrically or thermally conductive material – To form ohmic contact to semiconductive material

Reexamination Certificate

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C438S692000

Reexamination Certificate

active

06774030

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
Generally, the present invention relates to the field of manufacturing integrated circuits, and, more particularly, to the formation of so-called damascene structures in which metal trenches and vias are formed in an insulating layer, wherein the trenches and vias are formed prior to depositing the metal. Subsequently, the structure is planarized by removing the excess metal by chemical mechanical polishing.
2. Description of the Related Art
Typically, the fabrication of modern integrated circuits requires a huge number of individual process steps, wherein a typical process sequence involves the deposition of conductive, semiconductive or insulating layers on an appropriate substrate. After deposition of the corresponding layer, device features are produced by patterning the corresponding layer using well-known means, such as photolithography and etching. As a consequence, by patterning a deposited layer, a certain topography will be created that also affects deposition and patterning of subsequent layers. Since sophisticated integrated circuits require the formation of a plurality of subsequent layers, it has become standard practice to periodically planarize the surface of the substrate so as to provide for well-defined conditions for deposition and patterning of subsequent material layers. This holds true especially for so-called metallization layers in which metal interconnects are formed to electrically connect the individual device features, such as transistors, capacitors, resistors, and the like, to establish the functionality required by the circuit design.
Recently, the so-called damascene technique has become a preferred method in forming metallization layers wherein a dielectric layer is deposited and patterned to include trenches and vias that are subsequently filled with an appropriate metal, such as aluminum or copper. The excess metal is then removed, and the resulting surface is planarized by performing a chemical mechanical polishing (CMP) process. Chemical mechanical polishing has proven to be a reliable technique to remove the excess metal and planarize the resulting surface so as to leave behind metal trenches and vias that are electrically insulated from each other as required by the corresponding circuit layout. Chemical mechanical polishing typically requires the substrate to be attached to a carrier, a so-called polishing head, such that the substrate surface to be planarized is exposed and may be placed against a polishing pad. The polishing head and polishing pad are moved relative to each other by individually moving the polishing head and the polishing pad. Typically, the head and pad are rotated against each other while the relative motion is controlled to achieve as uniform a material removal as possible. During the polishing operation, a slurry that includes at least one chemically reactive agent and possibly abrasive particles is supplied to the surface of the polishing pad.
One problem involved in the chemical mechanical polishing of substrates is the very different removal rates of differing materials, such as of a metal and a dielectric material from which the excess metal has to be removed. For instance, at a polishing state where the dielectric material and the metal are simultaneously treated, i.e., after the major portion of the metal has already been removed, the removal rate for the metal exceeds the removal rate for the dielectric material. This is desirable because all metal is reliably ablated from all insulating surfaces, thereby insuring the required electrical insulation. Thus, a metal trench or via may be recessed with respect to the surrounding insulating material resulting in a trench or via that exhibits an increased electrical resistance due to the reduced cross-sectional area. In order to more clearly demonstrate a typical damascene process, reference is made to
FIGS. 1
a
-
1
e.
FIGS. 1
a
-
1
e
schematically show cross-sectional views of a semiconductor structure
100
at various stages in fabricating a metallization layer according to a typical damascene process sequence.
In
FIG. 1
a
, the semiconductor structure
100
comprises a substrate
101
bearing circuit features (not shown) and an insulating cap layer on which metal lines are to be formed. A patterned dielectric layer
102
is formed over the substrate
101
and includes openings, for example, in the form of narrow trenches
103
and wide trenches
104
. The dielectric layer
102
may also comprise closely-spaced openings
109
. The openings for the trenches
103
,
109
and
104
are patterned in conformity with design rules to establish metal lines exhibiting the required electrical characteristics in terms of functionality and conductivity. For instance, the trench
104
is designed as a so-called wide line to provide for a low electrical resistance. The deposition of the dielectric material
102
, as well as the patterning of the trenches
103
,
109
and
104
, is carried out by well-known deposition and photolithography techniques.
FIG. 1
b
schematically depicts the semiconductor structure
100
after deposition of a metal layer
105
, for example, a copper layer when sophisticated integrated circuits are considered. As is evident from
FIG. 1
b
, the topography of the metal layer
105
will be affected by the underlying pattern of the dielectric layer
102
. The metal layer
105
may be deposited by chemical vapor deposition, sputter deposition or, as usually preferred with copper, by electroplating with a preceding sputter deposition of a corresponding copper seed layer. Although the precise shape of the surface profile of the metal layer
105
may depend on the deposition technique used, in principle, a surface shape will be obtained as shown in
FIG. 1
b.
Subsequently, the semiconductor structure
100
will be subjected to chemical mechanical polishing, in which, as previously mentioned, the slurry and polishing pad are selected to optimally remove the excess metal in the metal layer
105
. During the chemical mechanical polishing, the excess metal is removed and, finally, surface portions
120
of the dielectric material
102
will be exposed, wherein it is necessary to continue the polishing operation for a certain overpolish time to ensure clearance of the metal from all insulating surfaces in order to avoid any electrical short between adjacent metal lines. As previously mentioned, the removal rate of the dielectric material and the metal may significantly differ from each other so that upon overpolishing the semiconductor structure
100
, the copper in the trenches
103
,
109
and
104
will be recessed.
FIG. 1
c
schematically shows a typical result of chemical mechanical polishing of the structure shown in
FIG. 1
b
. As is evident from
FIG. 1
c
, during overpolishing the semiconductor structure
100
, different materials are simultaneously polished with different removal rates. The removal rate is also dependent, to some degree, on the underlying pattern. For instance, the recessing of the metals during the overpolish time, which is also referred to as dishing, as well as the removal of the dielectric material, also referred to as erosion, is significantly affected by the type of pattern to be polished. In
FIG. 1
c
, dishing and erosion at the wide trenches
104
, as indicated by
107
and
106
, respectively, are relatively moderate, whereas at the narrow lines
103
, dishing
107
and erosion
106
are significantly increased. In obtaining a required electrical conductivity, circuit designers have to take into consideration a certain degree of dishing and erosion. The situation described in
FIG. 1
c
may, however, significantly change when the deposition of the metal layer
105
is completed with an insufficient layer thickness.
In
FIG. 1
d
, the metal layer
105
has been deposited with a thickness
110
, which may not be appropriate to completely fill the wide line
104
. The incomplete filling of the wide line
104
may be caused by any variations in the deposition process use

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