Manufacture of hydrocarbons from oxygenates

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – From nonhydrocarbon feed

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585408, C07C 100

Patent

active

043118658

ABSTRACT:
This invention provides a novel catalyst exemplified by cobalt-exchanged ZSM-5. The catalyst has unusual resistance to irreversible steam degradation. After long-term exposure to steam, it may be regenerated by sulfiding. The invention further provides a process for converting, in the presence of steam, compounds subject to catalytic conversion by acidic catalysts, including a process in which steam is inherently produced. The latter conversion is exemplified by the formation of higher carbon-numbered hydrocarbons from the lower alcohols or ethers thereof.

REFERENCES:
patent: 3804746 (1974-04-01), Chu
patent: 3992466 (1976-11-01), Plank et al.
patent: 4076761 (1978-02-01), Chang et al.
patent: 4100262 (1978-07-01), Pelrine

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