Manufacture of cellulosic particles

Details Manufacture of cellulosic particles Manufacture of cellulosic particles

2000-08-04

2003-01-07

Nguyen, Dean T. (Department: 3629)

Paper making and fiber liberation

Processes and products

Synthetic fiber

C162S157700, C162S182000, C162S164100

Reexamination Certificate

active

06503371

ABSTRACT:

FIELD OF THE INVENTION
This invention relates to methods for the manufacture of cellulosic particles of the kind known as fibrids.
Cellulosic fibrids can be made by mixing together under turbulent conditions a spinning solution of cellulose and a coagulating liquor. One example of such a solution is viscose, which contains sodium cellulose xanthate. Examples of coagulating liquors for viscose include aqueous salt solutions and aqueous acid solutions. The fibrids so produced comprise, often predominantly, fine fibrous particles a few microns in diameter; of comparable size to the fibres in woodpulp. These fibrids may also comprise platelike or globular particles of similar size to those fibres and of more or less irregular shape. For example, in the familiar salt figure test for viscose ripeness, viscose is mixed with aqueous sodium chloride. If the sodium chloride concentration is too low, a solution is formed; if it is too high, a more or less coherent precipitated lump is formed; but at the correct concentration, fibrids are formed. The fibrids formed in the salt figure test contain residual xanthate groups. If such fibrids are acidified, or if an acidic coagulating liquor is used, then the xanthate groups are destroyed and cellulose is regenerated.
BACKGROUND ART
Modified cellulose particles have been proposed as additives in papermaking, in particular to assist in formation of the paper web (sheet) and in sludge dewatering. In a series of papers in Das Papier (1980, vol. 34, pp. 575-579; 1981, vol. 35, pp. V33-V38 and pp. 555-562; and 1983, vol. 37, pp. 181-185), Kaufer et al. disclose cationically-modified cellulose particles prepared by the reaction of woodpulp with reagents such as 3-chloro-2-hydroxypropyltrimethylammonium chloride and the use of such particles as additives in papermaking.
Philipp and Lang (Faserforschung und Textiltechnik, 1966, vol. 17, pp. 299-304) disclose the addition of poly(ethyleneimine) to diluted viscose and titration of the resulting mixture with aqueous acid. A precipitate formed at mildly or moderately alkaline pH (8-11), depending upon the exact experimental conditions. The precipitate was described as a floc, indicating that it was composed of fibrids. The first-formed precipitate was believed to comprise a salt of a polymeric cation (protonated poly(ethyleneimine)) and a polymeric anion (cellulose xanthate). The authors refer to such salts generically as “symplexes”. Titration was continued until the mixture became acid (pH 3), and at least partial regeneration of cellulose xanthate to cellulose occurred, thus yielding cationically-modified cellulosic particles by a viscose process. Philipp and co-workers elsewhere propose the use of cationically-modified cellulose particles and symplexes as additives for use in papermaking (Dawydoff et al., Acta Polymerica, 1987, vol. 38, pp. 307-313, and Philipp et al., Progress in Polymer Science, 1989, vol. 14, pp. 91-172).
WO-A-96/26220 discloses a process in which a cationic polymer is added to diluted viscose and the resulting mixture is mixed with a coagulating and regenerating liquor such as dilute sulphuric acid to form cellulosic fibrids useful as additives in papermaking. The viscose was added to the coagulating liquor, or vice versa. The resulting slurry contained about 0.3, 0.5 or 1 percent of fibrids, and the fibrids were collected from it by filtration.
Cellulosic fibrids made from viscose may be collected from the aqueous slurry in which they are prepared by conventional methods such as settling, filtration and centrifugation. The cost of such collection varies generally in an inverse manner with the concentration of fibrids in the slurry. It is accordingly desirable on economic grounds to prepare slurries which contain high proportions of fibrids. Simple mixing, of the kind disclosed by Philipp and co-workers or in WO-A-96/26220, is not well-suited to the manufacture of slurries containing more than about 1 percent by weight of fibrids. These slurries are thick, semi-fluid, porridge-like materials which are difficult to mix. In consequence, addition of viscose to a preformed concentrated fibrid slurry carries the risk of coagulation occurring unevenly, resulting in the production of hard oversized particles rather than the desired fibrids. It is an object of the invention to provide a method of manufacturing fibrids wherein their collection from the aqueous slurry in which they are formed is simplified.
DISCLOSURE OF THE INVENTION
According to the present invention, there is provided a method for the manufacture of cellulosic fibrids by the viscose process, including the steps of:
(1) mixing together (a) viscose and (b) a coagulating and regenerating liquor under turbulent conditions, thereby forming a suspension of soft macroscopic cellulosic particles in a spent liquor;
(2) collecting the macroscopic particles from the spent liquor; and
(3) comminuting the macroscopic particles to form the fibrids.
The expression “spent liquor” is used as a convenient name for the byproduct liquor produced in the method of the invention; it will be appreciated that this liquor often retains some coagulating and regenerating powers.
The method of the invention preferably includes the additional step of:
(4) recovering the spent liquor for reintroduction as coagulating and regenerating liquor into step (1).
It is known that grain-like macroscopic cellulosic particles can be formed when viscose is contacted with a conventional coagulating and regenerating liquor; for example, if such particles are formed during fibre spinning, they constitute the defect known as trash. Such particles are generally hard and intractable. It is important in the present invention to choose conditions under which soft macroscopic particles are formed. Such conditions can readily be determined by simple experiment. The conditions which can be varied to achieve the desired aim include such factors as the composition, viscosity and degree of ripeness of the viscose; the composition of the coagulating and regenerating liquor; and the degree of shear. The soft macroscopic particles may resemble overcooked rice grains or soft cooked spaghetti. These particles are soft and friable, and they disintegrate under hand pressure. Particles in the form of “rice grains” are typically from 3 to 10 mm in size. Particles in the form of “spaghetti”, are typically from 3 to 5 mm in diameter and vary in length from 1 or 2 cm up to about 30 cm. The manufacture of particles in the form of “rice grains” is generally preferred, both for ease of collection and comminution and because fibrids from comminuted “rice grains” may have better properties than fibrids from comminuted “spaghetti”.
As guidance, we have found it convenient to employ a conventional viscose suitable for fibre manufacture and, prior to its introduction into mixing step (1), to mix it with water in a weight ratio in the approximate range from 1:2 to 10:1, preferably from 1:1 to 5:1. The cellulose concentration of the thusly diluted viscose may conveniently be in the range from 3 to 8, preferably from 5 to 7, percent by weight. The ballfall viscosity of the thusly diluted viscose may be in the approximate range from 5 to 30 seconds. We have generally found that, with increasing dilution and consequently reducing viscosity, the morphology of the particles progressively changes from spaghetti-like through rice-like to true fibrids. The formation of true fibrids indicates that the degree of dilution was excessive. If desired, the conventional viscose may be diluted with a slightly acidic liquor, for example with a liquor which includes a proportion of spent bath; provided that this does not result in any undue precipitation. This may offer advantages in terms of process economy.
The coagulating and regenerating liquor may be any of those known for viscose processes, particularly aqueous acid. Conveniently, it is dilute aqueous sulphuric acid, which is the most usual acidic component in such liquors, preferably at a concentration in the range from 0.5 to 5, more preferably from 1 to 3.5

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