Low dielectric constant material reinforcement for improved...

Active solid-state devices (e.g. – transistors – solid-state diode – Combined with electrical contact or lead – Of specified configuration

Reexamination Certificate

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C257S734000, C257S750000, C257S758000, C257S759000

Reexamination Certificate

active

06803662

ABSTRACT:

FIELD OF THE INVENTION
This invention is directed to the field of semiconductor manufacturing and more particularly to a method of reinforcing mechanically compliant dielectrics with mechanical supports.
BACKGROUND OF THE INVENTION
There are many factors which must be considered when designing the layout for a semiconductor interconnect system. Interconnect systems comprise different components. Two such components are the interlevel dielectrics and the metal line/via structures that are formed. For example, as ever increasing chip speeds are contemplated more complex interlevel dielectrics are being considered. The dielectrics are typically polymers that tend to have the advantage of lower dielectric constants (low k). Some of the low k dielectrics, which also have several advantages for processing purposes, do not have the mechanical integrity of their higher dielectric constant counterparts. By mechanical integrity it is meant that the low k dielectrics are mechanically compliant materials with a small Young's modulus. The mechanical integrity of the chosen low k dielectric can effect the speed and reliability of the overall semiconductor chip.
There are a number of different ways that a metallization can be formed. Two of the more popular ways are reactive ion etching (RIE) and damascene processing. In RIE, the metallization is first deposited. The metal is then etched and voids created. Possible deposition methods include physical vapor deposition (PVD) and chemical vapor deposition (CVD). The dielectric is then deposited and the voids filled. The dielectric can be deposited by any means known in the art. Possible deposition methods include chemical vapor deposition (CVD), plasma enhanced CVD, high density plasma CVD, or spin-on glass process.
Damascene processes are widely used in the manufacture of semiconductor devices. Generally, in a damascene process, a dielectric layer is first deposited on a substrate, a portion of the dielectric layer is then removed by an etching process in accordance with a mask pattern, the etched areas in the dielectric layer are lined with a barrier metal and then filled with a metal, and finally the excess liner and metal deposited over the dielectric layer are removed in a planarization process. By this method, metal features such as vias or lines are formed on a substrate.
Vias and lines can be formed in separate damascene processes, known as single damascene. For example, to form a layer of metal lines on a substrate, a dielectric layer is first deposited, then a portion of the dielectric layer is etched according to a mask pattern which corresponds to the desired line pattern, a metal liner is then deposited on the dielectric layer and in the etched line areas in the dielectric layer, these etched line areas are then filled with a metal, and finally the excess metal and liner on top of the dielectric layer is removed in a planarization process. A layer of vias is formed in a similar process, except that the mask pattern corresponds to the desired via pattern. Thus, to form a layer of vias and lines, two metal fill steps and two metal planarization steps are required.
In the electronics industry, there is a current trend toward using more cost effective dual damascene in the fabrication of interconnection structures. In a dual damascene process, both the via and the line are formed in the same damascene process. In one way to form the via and the line in the same damascene process, a thicker dielectric layer is first deposited on a substrate, the dielectric layer is then etched according to a mask pattern which corresponds to both the desired via pattern and the desired line pattern, a liner is then deposited on the dielectric layer and in the etched areas in the dielectric layer, these etched areas are then filled with a metal, and the excess metal and liner is removed by a planarization process. This dual damascene process therefore reduces the number of costly metal fill and planarization steps. It should be realized that in some dual damascene processes the via and line patterns can be defined in separate lithography and etch steps.
However, it is well known that interconnection structures are susceptible to failure caused by electromigration effects. For example,
FIG. 1
illustrates a cross sectional view of a wafer stack
100
formed using a conventional dual damascene process. The wafer stack
100
includes a substrate
102
, an oxide layer
104
, a metal layer
106
, a dielectric layer
108
, a liner
110
, a metal via
112
and a metal line
114
. The metal via
112
and metal line
114
are formed by a dual damascene process in which the dielectric layer
108
is first deposited on top of the metal layer
106
, the dielectric layer
108
is then etched to form via
112
and trench
114
according to a mask pattern which defines the desired via and line pattern, the liner
110
is deposited on the dielectric layer
108
and in the etched portions of the dielectric layer
108
, a metal is then deposited in the via
112
and trench
114
, and finally the excess metal and liner on top of the dielectric layer
108
are removed by a planarization process.
In this wafer stack configuration, when an electric potential is applied across the metal via
112
and metal line
114
, the electric potential causes an electromigration effect in the metal via
112
and metal line
114
. Specifically, the electric potential causes one portion of the interconnect structure to be a cathode and the other portion to be an anode. While there is no demarcation in a metal line for the end of the cathode end and the beginning of the anode end, for the purposes of this invention the anode end of the line shall be equal to at most 50% of the line length. The electric potential between the cathode and the anode causes a current flow from the anode end to the cathode end through metal via
112
and metal line
114
. Since the direction of electrons is opposite of the direction of current flow, the electron current is from the cathode end of the metal via
112
toward the anode end of the metal line
114
. In this process, the moving electrons generate an “electron wind” which pushes or forces the metal atoms in the direction of the electrons from the metal via
112
near the cathode to the metal line
114
near the anode. The liner
110
prevents the atoms in the metal layer
106
from migrating to the metal via
112
and metal line
114
. As a result, a void
116
forms near the cathode in the metal via
112
. The formation of this void often leads to catastrophic failure of the device. The failure is catastrophic because the liner
110
at the bottom of the via
112
is often thinner than in the line and therefore is unable to shunt the current across the void.
Also, metal atoms tend to pile up near the anode end of the interconnects during electromigration. The accumulation of metal atoms creates mechanical compressive stress which has the potential of creating cracks in the surrounding dielectric materials. As a result, the electromigrated metal atoms tend to extrude out through the cracks in the dielectric. The extruded material may then contact neighboring interconnects causing circuit failure (short circuit).
Void (and extrusion) formation due to electromigration is a well known phenomenon. Several methods have been proposed to counteract this electromigration effect in interconnects and thereby prevent void formation. For example, in IBM Technical Disclosure Bulletin Vol. 31, No. 6 (1988), tungsten (W) links are interposed periodically in long aluminum-copper (Al—Cu) lines or minimum groundrule features interfacing contact pads. These tungsten links form a physical barrier to the Al—Cu atoms being transported between the cathode to the anode. As another example, U.S. Pat. No. 5,470,788 to Biery et al. proposes interposing segments of Al with segments of refractory metal such as W.
Each of these methods is based on the existence of an electromigration threshold condition. Threshold conditions occur in adjacent levels of interconnections if an e

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