Lithographic plate precursor

Details Lithographic plate precursor Lithographic plate precursor

1999-07-08

2001-07-24

Chu, John S. (Department: 1752)

Radiation imagery chemistry: process, composition, or product th

Imaging affecting physical property of radiation sensitive...

Making printing plates

C430S157000, C430S158000, C430S160000, C430S175000, C430S176000, C430S944000

Reexamination Certificate

active

06265136

ABSTRACT:

BACKGROUND OF THE INVENTION
This invention relates to a method of producing a lithographic plate precursor which is imageable by direct heat and processable with water.
Currently the commonest method of preparing a lithographic plate is to image a photosensitive lithographic plate to UV light and to prepare the plate therefrom using an aqueous developing solution.
The differentiation between image and non-image areas is made in the exposure process. In conventional lithography a film original is applied to the plate with a vacuum to ensure good contact and the plate is then blanket exposed to a light source, a portion of which is composed of UV radiation.
More recent developments in the field of lithographic printing plates have provided imaging devices which allow for the preparation of direct digitally written printing forms. In the commonest method digital imaging information is used to image the plate directly by laser radiation without the need to utilise an imaging master such as a photographic transparency. The fastest growing trend is to utilise lasers which emit infra-red radiation. Such imaging systems are, however, costly due to the lasers required and this is a contributing factor to the slow rate of uptake of this new imaging technology within the print industry. However, imaging devices are now available commercially which can image media using direct heat via means of a heated stylus or nib controlled by an image stored in a computer. Such devices are much cheaper than the equivalent laser imagers and are reducing the entry cost for direct plate imaging systems. Following the exposure the differentiation is revealed during the development step. For typical negative acting systems this involves washing away material from the plate which was not imaged by the exposing source with the aid of a developing solution which may be highly alkaline, e.g. pH of 13, and based on an organic solvent. When aqueous developing solutions comprising volatile organic solvents or which are strongly alkaline in nature are used, their use and disposal presents an environmental problem.
SUMMARY OF THE INVENTION
We have discovered a method of preparing a negative working lithographic printing plate which can be processed with pure water and which can be imaged using direct heat combining both the compatibility with low cost imaging systems and the environmental benefits of water-only processing.
According to the present invention there is provided a method of preparing a lithographic printing plate which comprises coating on a lithographic support having a hydrophilic surface a layer of a heat sensitive coating, imaging the coating by direct heat and then processing the plate with water to remove the unexposed areas of the coating, to reveal the hydrophilic surface of the plate and to leave an ink receptive image, wherein the heat sensitive coating comprises a diazo salt of the following formula:
wherein R
1
is an anion, R
2
and R
3
represent optional substitution, R
4
is —N— or —S— and R
5
is a group which after exposure of the plate renders the residue of the diazo salt oleophilic and fount insoluble.
Usefully R
1
is sulphate, nitrate or chloride or it may be a more complex anion for example perfluorooctyl. R
2
and R
3
if present are preferably selected from an alkoxy, halogen, alkyl or amine. The presence of a substituent group in R
2
or R
3
helps to stabilise the diazo compound.
When R
4
is —N— it may be represented by
where R
7
and R
6
may be part of a polymer chain or may be part of a morpholino functional group.
Preferably however R
6
is hydrogen and R
7
is a group
where R
8
is the residue of a condensing agent and n is 1 to 100.
Thus the group R
7
converts the diazo compound to a diazo resin and this helps to prevent the exposed diazo from washing off during processing.
Examples of diazo salts usefull in the present invention are as follows:
In a preferred method of the present invention the printing plate precursor is, imagewise heated using a direct heat source which is imagewise controlled by an image stored in a computer.
Preferably the heat sensitive coating comprises a compound capable of absorbing heat and transferring this into the bulk of the coating. The heat absorbing material may be carbon such as carbon black or graphite. It may be a commercially available pigment such as HELIOGEN® Green as supplied by BASF or Nigrosine Base NGI as supplied by NH Laboratories Inc. Usefully it may be an organic pigment or dye such as phthalocyanine pigment or it may be a dye or pigment of the squarylium, merocyanine, indolizine, pyrylium or metal dithioline classes.
Several types of support may be used for the manufacturing of a diazo sensitised lithographic printing plate. Common supports are metal supports like Al or Zn, polyester film supports and paper bases. These supports, if not sufficiently hydrophilic by themselves, are first coated with a hydrophilic layer to form the hydrophilic background of the printing plate and a top layer containing the diazo compound is then applied.
Preferably the support is a flexible support which is attached to a printing press after the direct imaging and water development of the image.
In a modification to the method of the present invention there is present between the hydrophilic surface of the support and the dried diazo coating solution a hydrophilic layer. This helps the water to remove the unexposed diazo coating more cleanly after the imagewise exposure.
Examples of such hydrophilic layers are layers composed of hydrophilic polysaccharides, for example dextran or pullulan.


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WIPO Publication No. WO 99/00703.
WIPO Publication No. WO 98/32053.

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