Linear functional copolymers of ethylene with precise and...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S318000, C526S337000, C526S348000

Reexamination Certificate

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07402642

ABSTRACT:
The present invention is related to a linear functional polymer having repeating units A, B and D. Unit A represents —CH2—, unit B representsand unit D representswhere R1represents a polar functional group. There are at least four A units separating each B unit, each D unit, and each B and D unit. The value y represents the total number of B units and is an integer greater than or equal to 1. The total number of D units is represented by h and is an integer greater than or equal to 0. And x represents the total number of A units and is an integer sufficient that the molar fraction of the B and D units in the linear functional polymer is represented by a value j defined by the equation:j=y+hx+y+h≤0.032.The present invention is also directed to a method for preparing such linear functional polymers by copolymerizing a first polar substituted monomer and a second non-polar unsubstituted monomer.

REFERENCES:
patent: 5684108 (1997-11-01), Muller et al.
patent: 4341528 (1993-12-01), None
patent: 0108240 (1983-09-01), None
patent: 10-2001-0036073 (2001-05-01), None
patent: WO03078499 (2003-09-01), None
patent: WO 2003078499 (2003-09-01), None
Schwendeman et al., Functionalized Polyethylene Synthesis via Admet Chemistry, NATO Sci Ser. 11 (Math Phys Chem) vol. 56, pp. 307-319.
Partick M. O'Donnell, Kenneth B. Wagener; “Graft Copolymers by Acyclic Diene Metathesis and Atom Transfer Radical Polymerization Techniques,” Journal of Polymer Science: Part A: Polymer Chemistry, vol. 41, pp. 2816-2827 (2003).
Hongli Yang, Manirul Islan, Charles Budee, Stuart J. Rowan; “Ring-Opening Metathesis Polymerization as a Rout to Controlled Copolymers of Ethylene and Polar Monomers: Synthesis of Ethylene- Vinyl Chloride-Like Copolymers,” Journal of Polymer Science: Part A: Polymer Chemistry, vol. 41, pp. 2107-2116, (2003).
Bob R. Maughon and Robert H. Grubbs, “Synthesis and Controlled Cross-Linking of Polymers Derived from Ring-Opening Metathesis Polymerization (ROMP),” Macromolecules, vol. 29, No. 18, Aug. 26, 1996.
S. Ramakrishnan and T.C. Chung, “Poly(5-hydroxyoctenylene) and Its Derivatives: Synthesis via Metathesis Polymerization of an Organoborane Monomer,” 6019 Macromolecules, 23 Oct. 15, 1990, No. 21, Washington, D.C.
Albert Demonceau, et al., “Novel Ruthenium-Based Catalyst Systems for the Ring-Opening Metathesis Polymerization of Low-Strain Cyclic Olefins” 1997 American Chemical Society, Macromolecules, vol. 30, No. 11, Jun. 2, 1997 (pp. 3127-3136).
Lynda Johnson, et al., “Copolymerization of Ethylene and Acrylates by Nickel Catalysts” Polymeric Materials: Science & Engineering 2002, 86, 319.
Artur Michalak et al., “Theoretical Studies on the Polymerization and Co-Polymerization Processes Catalyzed by the Late-Transition-Metal Complexes” Polymeric Materials: Science & Engineering 2002, 86, 316.
Oren A. Scherman, et al. “Synthesis of Regioregular and Stereoregular Ethylene vinyl Alcohol CoPolymers Via Romp of a Protected Cyclooctene-5,6-(CIS and TRANS)-Diol” Polymer Preprints 2003, 44(1), 952.
Kurt Breitenkamp, et al., “Pegylated Poly(Cyclooctene) and Polyethylene” Polymer Preprints 2002, 43(2), 725.
Andreas W. Stumpf, et al. “Ruthenium-based Catalysts for the Ring Opening Metathesis Polymerisation of Low-strain Cyclic Olefins and of Functionalised Derivatives of Norbornene and Cyclooctene” J. Chem. So., Chem. Commun., 1995 (pp. 1127-1128).
T. C. Chung, “Synthesis of Alternating Vinyl Alcohol Copolymers” Polymer, 1991, vol. 32, No. 7 (pp. 1336-1339).
T.C. Chung, “Synthesis of Functional Polymers via Borane Monomers and Metathesis Catalysts” Journal of Molecular Catalysis, 76 (1992) pp. 15-31.
J.E. Schwendeman et al. “Functionalized Polyethylene Synthesis via Admet Chemistry” NATO Sci Ser. 11 (Math Phys Chem) vol. 56, pp. 307-319 (2002).
T.C. Chung et al. “Organoborane-Mediated Synthesis of Functional Polymers: A Review” Heteroatom Chemistry, vol. 1, No. 5, 1991 (pp. 545-552).
K. B. Wagener et al. “Precisely Branched Polyethylene and Other Very Regular Polymer Structures via Admet Chemistry” ACS Polymer Preprints 1998, 38(1), pp. 719-720.
S. J. McLain, et al. “New Routes to Ester and Acid Functionalized Polyethylene” Polymeric Materials Science & Eng. (1997), 76, 246-247.
Dominick J. Valenti et al. “Acyclic Diene Metathesis (ADMET), Polymerization of Alcohol functionalized Olefins” Polymer Preprints (Amer. Chem. Soc.) 1996, 37(2) 325-326.
Elite Drent et al. “Palladium Catalysed CoPolymerisation of ethane with alkylacrylates: Polar Comonomer built into the Linear Polymer Chain” The Royal Soc. of Chemistry 2002, Chem. Commun. 2002, 744-745.
A.F. Noels et al. “Metathesis of Low-Strain Olefins and functionalized Olefins with New Ruthenium-Based Catalyst Systems” NATO ASI Series, Ser. C. Math. & Phys. Sciences (1998), 506 (Metathesis Polymerization of Olefins andPolymerization of Alkynes) 29-46.
C.H. Stephens, “Characterization of Polyethylene with Partially Random Chlorine Substitution” Journal of Polymer Science: Part B, Polymer Physics, vol. 41, 2062-2070 (2003).
John C. Sworen et al., “Modeling Random Methyl Branching in Ethylene/Propylen Copolymers Using Metathesis Chemistry: Synthesis and Thermal Behavior” J. Am. Chem. Soc. 2003, 2228-2240.
Yavuz Imamoglu, “Metathesis Polymerization of Olefins and Polymerization of Alkynes” NATO ASI Series. Ser. C: Math & Phys. Scien. vol. 506, pp. 277-296 (1998).

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