Internally coated reaction vessel for use in olefinic polymeriza

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymerizing in reactor of specified material – or in reactor...

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526344, C08F 218, C08F 220, C08F 1406

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active

040680592

ABSTRACT:
This invention relates to a polymerization reaction vessel having a coating on the inner surfaces thereof resulting from applying thereto a coating composition containing, as a primary ingredient, an alkali soluble dye dissolved in an aqueous alkali metal hydroxide solution or an ammonium hydroxide solution. When polymerizing olefinic monomers, such as vinyl halides, vinylidene halides, and vinylidene monomers having at least one terminal CH.sub.2 =C< grouping, and mixtures thereof, in the presence of said coating, polymer build-up on the inner surfaces of the reaction vessel is substantially eliminated. Further, multiple charges or batches of polymer can be made in said internally coated reaction vessel without opening the same between charges thus preventing the escape of unreacted monomer to the atmosphere.

REFERENCES:
patent: 3669946 (1972-06-01), Koyanagi et al.
patent: 3959235 (1976-05-01), Nishigaki et al.
patent: 4024301 (1977-05-01), Witenhafer et al.
patent: 4024330 (1977-05-01), Morningstar et al.

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