Intermediate passivation and cleaning of compound semiconductor

Adhesive bonding and miscellaneous chemical manufacture – Delaminating processes adapted for specified product – Delaminating in preparation for post processing recycling step

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156655, 156662, 252 792, 2504922, H01L 21306, B44C 122, C03C 1500, C03C 2506

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active

045978255

ABSTRACT:
Crystalline compound semiconductors are passivated with a layer of the most volatile element thereof to prevent the formation of oxides that would interfere with further processing. A GaAs crystal is provided with a surface layer of arsenic. The arsenic layer is formed by exposure to light having a photon energy greater than 1.8 eV, at a power density of 0.01 to 0.5 watts per cm.sup.2 while the GaAs immersed in a 1:1 HCl:H.sub.2 O solution for a period of 10-30 minutes. The intermediate processing passivated GaAs crystal may be stored and handled in air and the As layer is removed by low temperature baking.

REFERENCES:
patent: 4351706 (1982-09-01), Chappell et al.
J. Vac. Sci. Technol., 19(2), Jul./Aug. 1981, Protection of Molecular Beam Epitaxy Grown Al.sub.x Ga.sub.1-x As Epilayers During Ambient Transfer by S. P. Kowalczyk et al., pp. 255-256.
J. Vac. Sci. Technol., 21(2), Jul./Aug. 1982, Peroxide Etch Chemistry on <100> I No. 53 (Ga 0.47 As by D. E. Aspnes et al., pp. 413-416.

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