Infrared emission detection of a gas

Radiant energy – Invisible radiant energy responsive electric signalling – Infrared responsive

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25033908, 25033913, 356311, G01N 2171, G01N 2162

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054731623

ABSTRACT:
Apparatus and method for qualitatively and quantitatively analyzing infrared emission from excited molecules in the determination of, for example, total inorganic carbon, chloride and available chlorine in aqueous samples. Methods of exciting the gas-phase, infrared-active molecules to emit radiation include flame excitation, furnace excitation, excitation by electron impact in a gas discharge or excitation by collisions with a vibrationally excited diatomic molecule. The detector is optimized by use of dual beam system with background subtraction capabilities thereby eliminating background noise and fluctuations therein.

REFERENCES:
patent: 2302554 (1942-11-01), Kingsbury
patent: 2349715 (1944-05-01), Francis
patent: 2458973 (1949-01-01), Barnes
patent: 2562525 (1951-07-01), Cary
patent: 3080483 (1963-03-01), Jaffe et al.
patent: 3210546 (1965-10-01), Perron
patent: 3516745 (1970-06-01), Schuman
patent: 3539807 (1970-11-01), Bickel
patent: 3561846 (1971-02-01), Kingsland
patent: 3594658 (1971-07-01), Cason
patent: 3679899 (1972-07-01), Dimeff
patent: 3689225 (1972-09-01), White
patent: 3696247 (1972-10-01), McIntosh et al.
patent: 3723831 (1973-03-01), Rogers
patent: 3749495 (1973-07-01), Wilkins et al.
patent: 3836255 (1974-09-01), Schuman
patent: 3854881 (1974-12-01), Cohen
patent: 3871768 (1975-03-01), Belcher et al.
patent: 3902808 (1975-09-01), Young
patent: 3902809 (1975-09-01), Sparks
patent: 3926522 (1975-12-01), Andreotti
patent: 4068125 (1978-01-01), Bell
patent: 4147431 (1979-04-01), Mann
patent: 4167334 (1979-09-01), Phillips
patent: 4249168 (1981-02-01), Muggli
patent: 4255051 (1981-03-01), Imamura et al.
patent: 4260884 (1981-04-01), Lovelock
patent: 4311485 (1982-01-01), Saltzman et al.
patent: 4408878 (1983-10-01), Fischbach
patent: 4466943 (1984-09-01), Murase et al.
patent: 4467435 (1984-08-01), Warnke et al.
patent: 4553152 (1985-11-01), Nishitani
patent: 4572668 (1986-02-01), Auth
patent: 4579461 (1986-04-01), Rudolph
patent: 4698314 (1987-10-01), Tao
patent: 4716293 (1987-12-01), Harrick
patent: 4730925 (1988-03-01), Chiba et al.
patent: 4810875 (1989-03-01), Wyatt
patent: 4849636 (1989-07-01), Fertig, Sr.
patent: 5007428 (1991-04-01), Watmough
patent: 5153673 (1992-10-01), Amirav
patent: 5246868 (1993-09-01), Busch et al.
Johansson et al, "A Multiple Grating Flame Photometer for the Simultaneous Determination of Five Elements", Spectrochimica Acta, 31B(7), 1976, pp. 419-428.
Plyer et al., Optical Systems for Increasing the Available Intensity from Flames, J. Opt. Soc. Amer., 42:360, 1952.
Bernard, B. B., A Summary of TOC Developments, O.I. Corporation, Jun. 1985.
Busch and Busch, "Signal-to-Noise Comparison of Flame Furnace Infrared-Emission (FIRE) Spectrometry with Room-Temperature, Nondispersive Infrared-Absorption Spectrophotometry," Applied Spectroscopy, 47(7):912-921, Jul. 1993.
Freeman and Hieftie, "Near-infrared Nonmetal Atomic Emission from a Helium Microwave-Induced Plasma. Element Ratio Determinations," Spectrochim Acta, 40B(4):653-664, 1985 (abstract only).
McGraw-Hill, Encyclopedia of Science and Technology, pp. 116-117 (1977).
Griffiths, "Infrared Emission Spectroscopy. I. Basic Considerations," Applied Spectroscopy, vol. 26, No. 1, 1972, 73-76.
Hudson et al. "Infrared Emission from a Flame as the Basis for Chromatographic Detection of Organic Compounds," Anal. Chem., 1987, 59, 2603-2609.
Davidchuck et al., "Unit for Investigating the Radiation Spectrum of the Combustion Products of Condensed Systems in the Range of 0.5-8uM," Combustion Explosion & Shock Waves, 10(5):683-685, 1974.
Hylton et al., "System for the Measurement of Spectral Emittance at High Temperature," AIAA Journal, 14(9):1303-1310, 1976.
Herget et al., "Remote Fourier Transform Infrared Air Pollution Studies," Optical Engineering, 19(4):508-514, 1980.
Gaydon, A. G., The Spectroscopy of Flames, Chapman and Hall, London, pp. 221-243, 1974.
Gaydon et al., Flames, Their Struction, Radiation and Temperature, 4th Ed., Chapman and Hall, London, pp. 238-259, 1979.
Plyler et al., "Infrared Radiation from a Bunsen Flame" J. Res. Nat. Bur. Stand., 40:113, 1948.
Nakamoto, K., Infrared Spectra of Inorganic and Coordination Compounds, John Wiley, New York, p. 77, 1963.
Curcio et al., "Transmission of Infrared Radiation from Flames by CO.sub.2 ", Appl. Opt., 5:231-233, 1966.
Putley, Optical and Infrared Detectors, Keyes (ed.) Springer-Verlag, Berlin, Chapter 3, 1980.
Boyd, Radiometry and the Detection of Optical Radiation, John Wiley, New York, Chapter 10, 1983.
Busch et al., "Simultaneous Determination of Electrolytes in Serum Using a Vidicon Flame Spectrometer", Busch et al., Anal. Chem., 46:1231, 1974.
Garrett, R. L., J. Pet. Tech., p. 860, Jun. 1978.
Small et al., International Laboratory, "Oxidation and Detection Techniques in TOC Analysis", May, 1986.
Small, "All About TOC Analyzers" Pollution Engineering, p. 53, Sep. 1980.
Capelle et al., Review of Scientific Instruments, 49(8):1124-1129, Aug., 1978.
Karger et al., An Introduction of Separation Science, Wiley, New York, pp. 232-236, 1973.
Greenberg et al., Eds, Standard Methods for the Examination of Water and Wastewater, American Public Health Association, Washington, D.C., pp. 286-294, 1985.
Manahan, S. E., Environmental Chemistry, 3rd Ed., Willard Grant Press, Boston, Massachusetts, p. 29, 1979.
Busch et al., "Flame/Furnace Infrared Emission Spectroscopy: New Ways of Playing with FIRE," Spectroscopy, 4(8):22-36, 1989.
Busch et al., "A High-Efficiency Light-Collection System for Energy-Limited Infrared Emission Radiometers," Applied Spectroscopy, 45(6):964-968, 1991.
Busch and Busch, "Analytical Applications of Flame/Furnace Infrared Emission Spectrometry," Spectrochimica Acta Rev., 14(4):303-336, 1991.
Busch and Busch, "Signal-to-Noise Considerations in Flame/Furnace Infrared Emission Spectroscopy," Applied Spectroscopy, 45(4):546-554, 1991.
Busch and Busch, "Flame Infrared-Emission--An Element-/specific Detector for GC," American Laboratory, 23(11):18, 1991. Abstract only.
Crane, "Selection of a TOC Analyzer," American Laboratory, pp. 51-58, 1988.
Hudson and Busch, "Flame Infrared Emission Detector for Gas Chromatography," Anal. Chem., 60:2110-2115, 1988.
Hudson and Busch, "Infrared Emission from a Flame as the Basis for Chromatographic Detection of Organic Compounds," Anal. Chem., 59:2603-2609, 1987.
Hudson and Busch, "Studies on the Feasibility of Using Infrared Emission from a Flame as the Basis for a Non-Selective Detector for Liquid Chromatography," Southwest Regional Meeting of ACS, Nov. 19, 1987, Abstract No. 234.
Kubala et al., "Determination of Total Inorganic Carbon in Aqueous Samples with a Flame Infrared Emission Detector," Analytical Chemistry, 61:1841-1846, 1989.
Kubala et al., "Determination of Chloride and Available Chlorine in Aqueous Samples by Flame Infrared Emission," Anal. Chem., 61:2785-2791, 1989.
Kubala et al., "Design and Performance of a Direct-Reading, Multichannel Spectrometer for the Determination of Chlorinated Purgeable Organic Compounds by Flame Infrared-Emission Spectrometry," Talanta, 38(6):589-602, 1991.
Lam et al., "An Investigation of the Signal Obtained from a Flame Infrared Emission (FIRE) Detector," Applied Spectroscopy, 44(2):318-325, 1990.
Lam et al., "Design and Performance of a New Continuous-Flow Sample-Introduction System for Flame Infrared-Emission Spectrometry: Applications in Process Anslysis, Flow Injection Analysis, and Ion-Exchange High-Performance Liquid Chromatogrphy," Talanta, 40(6):867-878, 1993.
Ravishankar et al., "Dual-Channel Flame Infrared Emission Detector for Gas Chromatograph," Anal. Chem., 62:1604-1610, 1990.
Ravishankar et al., "An Element-Specific, Dual-Channel, Flame Infrared Emission, Gas Chromatography Detector for Chlorinated and Fluorinated Hydrocarbons," Applied Spectroscopy, 44(8):1247-1258, 1990.
Ravishankar et al., "Spatial Emission Characteristics of a Capillary-Burner Excitation Source for a Flame Infrared Emission (FIRE) Radiometer," Applied Spectroscopy, 45(10):1684-1694, 1991.
Thayer, "Analytical Instrumentation Market Growing Rapidly," C&EN, pp. 17

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