Indium-tin oxide (ITO) layer and method for producing the same

Chemistry: electrical and wave energy – Processes and products – Coating – forming or etching by sputtering

Reexamination Certificate

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C204S192220, C204S192260

Reexamination Certificate

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06849165

ABSTRACT:
A process for the deposition of transparent and conductive indium-tin oxide (ITO) films with a particularly low resistance of preferably less than 200 μΩcm and a small surface roughness of preferably less than 1 nm on a substrate, wherein combined HF/DC sputtering of an indium-tin oxide (ITO) target is employed and wherein the process gas is supplemented by an argon/hydrogen mixture as reaction gas during the sputtering, as well as ITO-films with the above-named characteristics.

REFERENCES:
patent: 02054755 (1990-02-01), None
patent: 05239635 (1993-09-01), None
patent: 09293693 (1997-11-01), None
“Effect of Hydrogen Partial Pressure on Optoelectronic Properties of Indium Tin Oxide Thin Films Deposited by Radio Frequency Magnetron Sputtering Method” by K. Zhang et al.,Journal of Applied Physics., vol. 86, No. 2, Jul. 15, 1999, pp. 974-980.
“Effect of Process Parameters on characteristics on Indium Tin Oxide Thin Film for Flat Panel Display Application” by H.L. Byung et al. Thin Solid Films, Elsevier-Sequoia S.A., Lausanne, CH, vol. 302, No. 1-2, Jun. 20, 1997, pp. 25-30.
“Low Resistivity Indium-Tin Oxide Transparent Conductive Films. I. Effect on Introducing H20 Gas or H2 Gas During Direct Current Magnetron Sputtering” by S. Ishibashi et al., Journal of Vacuum Science and Technology: Part A, American Institute of Physics, vol. 8, No. 3, Part 1, May 1990, pp 1399-1402.
“Indium Thin Oxide Films Prepared by Radio Frequency Magnetron Sputering Method at a Low Processing Temperature” by K. Zhang et al., Thin Solid Films, Elsevier-Sequoia S.A., Lausane, CH, vol. 376, No. 1-2, Nov. 1, 2000, pp 255-263.
“DC Magnetron Reactively Sputtered Indium-Tin-Oxide Films Produced Using Argon-Oxygen-Hydrogen Mixtures” by G.L. Harding et al., Solar Energy Materials, Elsevier Science Publishers B.V., Amsterdam, NL, Nos. 5/6, pp. 367-379.
“Electrical Characterization of ITO/p-InP Solar Cells”, by Z.A. Shi et al., 23rdIEEE Photovoltaic Specilists Conference, May 14, 1993, pp. 1432-1436.
“Optimized Indium Tin Oxide Contact for Organic Light Emitting Diode Applications” by F. Zhu et al., Thin solid Films, Elsevier-Sequoia S.A., Lausanne, CH, 2000, No. 1/2, pp. 314-317.

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