Imino-amide catalysts for olefin polymerization

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

Reexamination Certificate

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C556S012000, C556S032000, C556S051000, C502S167000

Reexamination Certificate

active

10923597

ABSTRACT:
The present invention provides a catalyst precursor, a catalyst system comprising the precursor, and a polymerization method using the catalyst system, an embodiment of the precursor is selected from the following structures:wherein T is a bridging group; M is selected from Groups 3 to 13 atoms, and the Lanthanide series of atoms the Periodic Table of the Elements; Z is a coordination ligand; each L is a monovalent, bivalent, or trivalent anionic ligand; X and Y are each independently selected from nitrogen, oxygen, sulfur, and phosphorus; each R can be the same or different and is a bulky substituent that is sterically hindering with respect to X and Y.

REFERENCES:
patent: 5707913 (1998-01-01), Schlund et al.
patent: 6096676 (2000-08-01), Murray
patent: 6174975 (2001-01-01), Johnson et al.
patent: 6197714 (2001-03-01), Bansleben et al.
patent: 6262198 (2001-07-01), Schlund et al.
patent: 6265505 (2001-07-01), McConville et al.
patent: 6268448 (2001-07-01), Collins et al.
patent: 6271323 (2001-08-01), Loveday et al.
patent: 6274684 (2001-08-01), Loveday et al.
patent: 6281306 (2001-08-01), Oskam et al.
patent: 6300438 (2001-10-01), McConville
patent: 6320002 (2001-11-01), Murray et al.
patent: 6320005 (2001-11-01), Murray
patent: 6380328 (2002-04-01), McConville et al.
patent: 6399722 (2002-06-01), Szui et al.
patent: 6399724 (2002-06-01), Matsui et al.
patent: 6410660 (2002-06-01), Johnson et al.
patent: 6410664 (2002-06-01), Bansleben et al.
patent: 6417304 (2002-07-01), McConville et al.
patent: 6458738 (2002-10-01), Cook
patent: 6472342 (2002-10-01), Agapiou et al.
patent: 6475946 (2002-11-01), Rix
patent: 6479422 (2002-11-01), Eilerts
patent: 6482903 (2002-11-01), Agapiou et al.
patent: 6489414 (2002-12-01), Schuchardt
patent: 6489497 (2002-12-01), Brookhart et al.
patent: 6511936 (2003-01-01), Theopold et al.
patent: 6518444 (2003-02-01), McConville et al.
patent: 6521561 (2003-02-01), Jacobsen et al.
patent: 6544919 (2003-04-01), Tagge et al.
patent: 6559091 (2003-05-01), Moody et al.
patent: 6579823 (2003-06-01), Moody et al.
patent: 6579998 (2003-06-01), Sita et al.
patent: 6586358 (2003-07-01), Llatas et al.
patent: 6593266 (2003-07-01), Matsui et al.
patent: 6610627 (2003-08-01), Murray
patent: 6632769 (2003-10-01), Wenzel et al.
patent: 6632770 (2003-10-01), Holtcamp
patent: 6660677 (2003-12-01), Mackenzie et al.
patent: 6660679 (2003-12-01), Holtcamp et al.
patent: 6660815 (2003-12-01), Agapiou et al.
patent: 6670297 (2003-12-01), Brookhart et al.
patent: 6686491 (2004-02-01), Cavell et al.
patent: 6831187 (2004-12-01), Murray
patent: 6864205 (2005-03-01), Murray
patent: 6919467 (2005-07-01), Murray
patent: 2002/0120081 (2002-08-01), Guan
patent: 2003/0153697 (2003-08-01), Boussie et al.
patent: 2005/0003075 (2005-01-01), Bradley et al.
patent: 2005/0159303 (2005-07-01), Boussie et al.
patent: 2005/0288505 (2005-12-01), Liang
patent: 2006/0094591 (2006-05-01), Gibson et al.
patent: 4202889 (1993-08-01), None
patent: 0320169 (1989-06-01), None
patent: 0509233 (1992-10-01), None
patent: 0349886 (1995-09-01), None
patent: 0761694 (1997-03-01), None
patent: 0803520 (1997-10-01), None
patent: 0950667 (1999-10-01), None
patent: 2000128922 (1998-10-01), None
patent: 2000-128922 (2000-05-01), None
patent: WO-9212162 (1992-07-01), None
patent: WO-9533497 (1995-12-01), None
patent: WO-9623010 (1996-08-01), None
patent: WO-9633202 (1996-10-01), None
patent: WO-9702298 (1997-01-01), None
patent: WO-9745434 (1997-12-01), None
patent: WO-0246246 (2002-06-01), None
Cotton et al, “Advanced Inorganic Chemistry A Comprehensive Text,” John Wiley & Sons, 776-778, 790, 792-793 (1980).
Gibson et al, “Synthesis and structural characterization of aluminum imino-amide and pyridyl-amide complexes: bulky monoanionic N,N chelate ligands via methyl group transfer,” Journal of Organometallic Chemistry 550, 453-456, 1998.
Fuhrmann et al, “Octahedral Group 4 Metal Complexes that contain Amine , Amido and Aminopyridinato Ligands: Synthesis, Structure, and Application in a-Olefin Oligo- and Polymerization,” Inorg. Chem 35, Feb. 1996, pp. 6742-6745.
Briotovsek et al, “Novel Olefin Polymerization Catalysts Based on Iron and Cobalt,” Chem Commun. May 1998, pp. 849-850.
Deelman et al, “Lithium Derivatives of Novel Monoaniomic Di-N-N- chelating Pyridyl- and Quinolyl-I-azaallyl Ligands,” Organometalics 16, Aug. 1997, pp. 1247-1252.
Deelman et al, “Novel monanionic di-N-N- centered chealting ligands and the C1 and C2 symmetrical zirconium complexes,” Jurnal of Organomettalic Chemistry 513, Nov. 1996, pp. 281-285.
Hitchcock et al, “Transformation of the Bis(trimethylsily) methyl into Aza-allyl and B-Diketinimato Ligands: the X-Ray Structures of [li{N(R)C(Bu1)CH(R)}]2 and [Zr{N(R)C(Bu1)CHC(Ph)N(R)}C13] (R=SiMe3)” J. Chem. Soc., Chem Comm. Aug. 1994, pp. 2637-2638.
Hitchcock et al, “Transformation of the Bis(trimethylsily)methyl into a B-Diketinimato Ligand: the X-Ray Structure of [Li(IL'L')]2 SNCi(Me)2 (L'L') amd SnCi(Me)2(LL), (L'L') (L'L'= N(R)C(Ph)NRLL=N)H)C(Ph)NH, R—SiMe3)” J. Chem. Soc., Chem Commun. May 1994, pp. 1699-1700.
Clarke et al, “Structural Investigations of the Dipyrromethene Complexes of Calcium(II), Nickel(II) and Copper(II),” Inorganica Chimica Acta. 166, Jun. 1989, pp. 221-231.
Tjaden et al, “Synthesis, Structures, and Reactivity of (R6-acen)ZRR2 and (R6-acenZR(R') Complexes (R=H, F: R'=CH2Cme3, CH2PH),” Organmetallics 14, Jul. 1995, pp. 371-386.
Corazza et al, cis and trans Dichloro-derivatives of Six and Seven co ordinate Zirconium and Hafnium bonded to Quadridentate Schiff-base Ligands. Crystal Structures of [Zr(acen)Cl2(thf)], [M(salphen)Cl2(thf)] 0.5thf, [M9acen)Cl2. (M=Zr of Hf), and [Zr(msal)Ci2] acen=N,N'=ethylenebis (acetylacetoneiminate), salphen=N,N'-o-phenylenebis (salicylideneiminate), msal=N-methylsalicylideneiminate, and thf=tetrahydrofuran] J. Chem. Soc. Dalton Trans. Aug. 1990, pp. 1335-1344.
Cozzi et al, “Oxazoline Early Transition Metal Complexes: Functionalizable Achiral Titanium(IV), Titanium (III), Zirconium(IV), Vanadium(III), and Cj=hiral Zirconium(IV) Bls(oxazoline) complexes” Inorg. Chem 34, Dec. 1995, pp. 2921-2930.
Korine et al, “Bis(Trimethylsily)benzamidinate zirconium dichlorides. Active catalysts for ethlene polymerization.” Journal of Organometallic Chemistry 503, Mar. 1995, pp. 307-314.
Gomez et al, “Mono-n-cyclopendtadienyl-benzamidinato chloro compounds of titanium, zirconium and hafnium,” Journal of Organmetallic Chemistry 491, Aug. 1995, pp. 153-158.
Flores et al, “[N,N-Bis(trimethylsily)benzamidinato]titanium and zirconium Compounds. Synthesis and Application as Persursors for the Syndiospecific Polymerization of Styrene,” Organomettalics 14, Oct. 1995, pp. 1827-1833.
Dias et al, “N-Methyl-29methylamino)troponiminate Complexes of Tin(II), Gallium(III), and Indium(III), Synthesis of [(ME)2ATI]2Gal and {(Me)2ATI 2InCl Using the Tin(III) Reagent [(Me02ATI]2SN,” Inorg. Chem. 35, Jun. 1996, pp. 6546-6551.
Cotton et al, “Structural Studies of formamidine compounds: from neutral to anionic and cationic species,” Polyheron vol. 16, No. 3, Apr. 1997, pp. 541-550.
Gornitzka et al., “Coordinationo of the Bis(pyridyl)methyl Substiuent to Group 1 and 13 Metals,” Organmetallics 13, May 1994, pp. 4398-4405.
Roesky et al, “Benzamidnatokomplexe mit Haupt- and Nebengruppen-Elementen—Strukturen von PhC(NSiMe3)2TiCl2 and PhC(NSiMe3)2MoO2,” Chem Ber. 121, Feb. 1988, pp. 1403-1406.
Cloke et al, “Zirconium Complexes incorporating the New Tridentate Diamide Ligand [(Me3Si)N{CH2CH2N(SiMe3)}2]2 (L); the Crystal Structure of [Zr(BH4)2L] and ZrCl{CH(SiMe3)2}L)” J. Chem Soc. Dalton Trans, Jul. 1995, pp. 25-30.
Linden et al., “Polymerization of a-Olefins and Butadiene and Catalytic Cyclotrimerization of 1-Alkynes by a New Class of Group IV Catalysts. Control of Molecular Weight and Polymer

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