Hydrocarbon conversion with an acidic multimetallic catalytic co

Details Hydrocarbon conversion with an acidic multimetallic catalytic co Hydrocarbon conversion with an acidic multimetallic catalytic co

1974-11-08

1976-06-01

Gantz, Delbert E.

Mineral oils: processes and products

Chemical conversion of hydrocarbons

Reforming

252441, 208111, 26068368, C10G 3508

Patent

active

039607100

ABSTRACT:
Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with an acidic multimetallic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a tin component, a cobalt component and a halogen component with a porous carrier material. The platinum group component, tin component, cobalt component, and halogen component are present in the multimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % tin, about 0.5 to about 5 wt. % cobalt, and about 0.1 to about 3.5 wt. % halogen. Moreover, these metallic components are uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum group metal is present therein in the elemental metallic state, substantially all of the cobalt component is present in the elemental metallic state or in a state which is reducible to the elemental metallic state under hydrocarbon conversion conditions, while substantially all of the tin is present therein in an oxidation state above that of the elemental metal. A specific example of the type of hydrocarbon conversion process disclosed is a process for the catalytic reforming of a low-octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the acidic multimetallic catalyst disclosed herein at reforming conditions.

REFERENCES:
patent: 2911357 (1959-11-01), Myers et al.
patent: 3576766 (1971-04-01), Ransch
patent: 3644198 (1972-02-01), Wilhelm
patent: 3775300 (1973-11-01), Hayes
patent: 3830727 (1974-08-01), Kluksdahl et al.
patent: 3844938 (1974-10-01), Wilhelm
patent: 3847794 (1974-11-01), Rausch
patent: 3881696 (1975-05-01), Lepeytre et al.

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