Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – And additional al or si containing component
Patent
1993-03-12
1994-10-25
Dees, Carl F.
Catalyst, solid sorbent, or support therefor: product or process
Zeolite or clay, including gallium analogs
And additional al or si containing component
502 68, B01J 2906
Patent
active
053589181
ABSTRACT:
A hydrocarbon conversion catalyst for converting petroleum distillates of different boiling ranges, residue oils, and crude oils, especially the heavy hydrocarbons containing high nickel, into high quality gasoline and C.sub.3 and C.sub.4 olefins. The catalyst of the invention comprises three zeolitic active components consisting of a rare-earth-containing pentasil type high silica zeolite ZRP, a REY zeolite, and a high silica Y zeolite, in a total content of 10-40 wt % based on the total weight of the catalyst, and the remainder synthetic matrix or semi-synthetic matrix comprising 10-40 wt % silica and/or alumina binder. In the total amount of the active components, zeolite ZRP, REY, and the high silica Y are 3-50, 12-75, and 12-75 wt % respectively. The zeolite ZRP used in the catalyst is characterized in an anhydrous chemical composition of the formula 0.01-0.30 RE.sub.2 O.sub.3.0.4-1.0 Na.sub.2 O.Al.sub.2 O.sub.3.20-60 SiO.sub.2 , a specific X- ray diffraction pattern, a higher adsorption capacity ratio of normal hexane to cyclohexane, and a rare earth ingredient which originates from a rare earth containing faujasite used as seed in the synthesis of the zeolite.
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Haibin Liu
Shuqin Zhang
Suxin Cui
Xingtian Shu
Yongqing Huo
China Petro-Chemical Corporation
Dees Carl F.
Research Institute of Petroleum Processing Sinopec
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