High temperature aqueous polymerization process

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526230, 526227, 526271, 526312, 5263182, 5263171, 5263184, 52631842, 5263076, 526287, 526278, 526264, 526259, C08F 430, C08F 216, C08F 2004

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052684377

ABSTRACT:
This invention relates to high temperature aqueous processes for the polymerization of monoethylenically unsaturated carboxylic monomers to produce low molecular weight, water-soluble polymer products useful as detergent additives, scale inhibitors, dispersants and crystal growth modifiers. Suitable monomers include acrylic acid, methacrylic acid, maleic acid, maleic anhydride, crotonic acid, and itaconic acid. The reactions are run at temperatures ranging from about 130.degree. C. to 240.degree. C., preferably from about 140.degree. C. to about 230.degree. C. The process can be continuous, semi-continuous, or batch.

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Spychaj, et al., High-Temperature Continuous Bulk Copolymerization of Styrene and Acrylic Acid: Thermal Behavior of the Reactants, pp. 2111-2119, Journal of Applied Polymer Science, vol. 42.

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