High-selective production method of...

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

Reexamination Certificate

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Reexamination Certificate

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10781884

ABSTRACT:
A di(aminomethyl)-substituted aromatic compound is produced by a two-stage hydrogenation. In the first stage, an aromatic dinitrile is hydrogenated into a cyano(aminomethyl)-substituted aromatic compound in the presence of a Pd-containing catalyst. The resultant cyano(aminomethyl)-substituted aromatic compound is then hydrogenated in the second stage into the target di(aminomethyl)-substituted aromatic compound in the presence of a Ni- and/or Co-containing catalyst. By the above method, the di(aminomethyl)-substituted aromatic compound is produced in a high selectivity and a sufficiently high yield without reducing the catalyst life.

REFERENCES:
patent: 3647054 (1972-03-01), Tsuboi et al.
patent: 6476267 (2002-11-01), Fuchigami et al.
patent: 77 983 (1970-12-01), None
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patent: 2002-205980 (2002-07-01), None
patent: 2003-327563 (2003-11-01), None
patent: WO 96/18603 (1996-06-01), None
Abstract of JP Patent No. 48022593, dated Jul. 6, 1973.
Abstract of JP Patent No. 38008719, dated Jun. 11, 1963.

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