Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing
Patent
1995-05-30
1997-10-21
Wu, David W.
Organic compounds -- part of the class 532-570 series
Organic compounds
Heavy metal containing
556 11, 556 12, 556 13, 556 19, 556 20, 556 21, 556 27, 556 52, 556 53, 502155, 526127, 526160, 526943, C07F 710
Patent
active
056798113
ABSTRACT:
A very efficient catalyst system for the polymerization of 1-olefins consists of an aluminoxane and a metallocene which is a compound of the formula I ##STR1## in which R.sup.1 and R.sup.2 denote hydrogen atoms, halogen atoms or hydrocarbon radicals and R.sup.3 and R.sup.4 are mononuclear or polynuclear hydrocarbon radicals which can form a sandwich structure with the central atom and which are linked to one another by a --R.sup.6.sub.m --R.sup.5 --R.sup.7.sub.n -- bridge containing a hetero atom and consisting of one or several members.
The catalyst system produces polymers having a high molecular weight.
REFERENCES:
patent: 4522982 (1985-06-01), Ewen
patent: 4536484 (1985-08-01), Lacombe et al.
patent: 4542199 (1985-09-01), Kaminsky et al.
patent: 4701432 (1987-10-01), Welborn, Jr.
patent: 4769510 (1988-09-01), Kaminsky et al.
patent: 4794096 (1988-12-01), Ewen
patent: 4808561 (1989-02-01), Welborn, Jr.
patent: 4897455 (1990-01-01), Welborn, Jr.
patent: 4933403 (1990-06-01), Kaminsky et al.
patent: 4937299 (1990-06-01), Ewen et al.
patent: 5017714 (1991-05-01), Welborn, Jr.
patent: 5084534 (1992-01-01), Welborn, Jr. et al.
patent: 5103030 (1992-04-01), Rohrmann et al.
patent: 5120867 (1992-06-01), Welborn, Jr.
patent: 5314973 (1994-05-01), Welborn, Jr.
Grant & Hackh's Chemical Dictionary (3d Ed.), p. 192 (1969).
Moor, Physical Chemistry, Prentice-Hall, NJ (1955), p. 116.
Ewen, J.A. et al., "Crystal Structures and Stereospecific Propylene Polymerization with Chiral Hafnium Metallocene Catalysts", J. Am. Chem. Soc. 1987, 109, 6544-6545 (1987).
Kaminsky et al., "Olefinpolymerization with Highly Active Soluble Zirconium Compounds Using Aluminoxane as Cocatalyst", Makromol. Chem., Macromol. Symp. 3, 377-387 (1986).
Kaminsky et al., "Transition Metals and Organometallics as Catalyst for Olefin Polymerization", Proceedings of an International Symposium, Hamburg, Sep. 21-24, 1987.
Antberg Martin
Dolle Volker
Rohrmann Jurgen
Spaleck Walter
Winter Andreas
Hoechst Aktiengesellschaft
Wu David W.
LandOfFree
Hafnium metallocene compound does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Hafnium metallocene compound, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Hafnium metallocene compound will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-1007836